Szczegóły publikacji

Opis bibliograficzny

Chitosan-based films with alternative eco-friendly plasticizers: preparation, physicochemical properties and stability / Weronika Janik, Kerstin Ledniowska, Michał Nowotarski, Stanisław Kudła, Joanna KNAPCZYK-KORCZAK, Urszula STACHEWICZ, Ewa Nowakowska-Bogdan, Ewa Sabura, Hanna Nosal-Kovalenko, Roman Turczyn, Gabriela Dudek // Carbohydrate Polymers ; ISSN 0144-8617. — 2023 — vol. 301 Pt. A art. no. 120277, s. 1–14. — Bibliogr. s. 12–14, Abstr. — Publikacja dostępna online od: 2022-10-29

Autorzy (11)

Słowa kluczowe

physico-chemical characterizationchitosanmechanical propertiesfilmsplasticizerpolysaccharide

Dane bibliometryczne

ID BaDAP143733
Data dodania do BaDAP2022-11-29
Tekst źródłowyURL
DOI10.1016/j.carbpol.2022.120277
Rok publikacji2023
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaCarbohydrate Polymers

Abstract

Chitosan-based films modified with synthesized (propylene glycol monoacetate, propylene glycol esters of fatty acids, and epoxidized propylene glycol esters) and commercial eco-friendly plasticizers (epoxidized soybean oil and epoxidized palm oil) were prepared by a casting technique, with the aim to obtain environmentally friendly materials for packaging applications. To assess the applicability of alternative plasticizers, their properties were compared to the two most common plasticizers, i.e. glycerol and sorbitol. The chemical structure of newly synthesized plasticizers was verified by gas chromatography with mass detector, infrared spectroscopy and 1H NMR; and their acid, epoxy, iodine, and saponification values were determined. Plasticized chitosan-based films were characterized in terms of hydrophilic, barrier, thermal, mechanical properties, zeta potential and morphology, confirming their flexibility and homogeneity. The research confirmed that the alternative plasticizers introduced by us are more effective than commercially available ones, exhibiting lower hydrophilicity and superior mechanical properties compared to samples plasticized with traditional plasticizers. Moreover, these properties were found to be even better after ageing for 10 months.

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