Szczegóły publikacji
Opis bibliograficzny
Crystal structure, electronic band structure and high-temperature thermoelectric properties of Te-substituted tetrahedrites $Cu_{12}Sb_{4-x}Te_{x}S_{13}$ $(0.5\leq x \leq 2.0)$ / Y. Bouyrie, C. Candolfi, O. Ohorodniichuk, B. Malaman, A. Dauscher, J. TOBOŁA, B. Lenoir // Journal of Materials Chemistry. C ; ISSN 2050-7526. — 2015 — vol. 3 iss. 40, s. 10476–10487. — Bibliogr. s. 10486–10487
Autorzy (7)
- Bouyrie Yohan
- Candolfi Christophe
- Ohorodniichuk V.
- Malaman Bernard
- Dauscher Anne
- AGHToboła Janusz Stefan
- Lenoir Bertrand
Dane bibliometryczne
| ID BaDAP | 94682 |
|---|---|
| Data dodania do BaDAP | 2016-01-27 |
| Tekst źródłowy | URL |
| DOI | 10.1039/c5tc01636c |
| Rok publikacji | 2015 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Journal of Materials Chemistry, C |
Abstract
Polycrystalline samples of the tetrahedrite phase Cu12Sb4-xTexS13 with nominal compositions 0.5 <= x <= 2.0 were synthesized by two different synthesis routes: from precursors and from direct melting of elements. The crystal structure was verified by single-crystal and powder X-ray diffraction (PXRD), both confirming the successful substitution of Te for Sb in both series. Our chemical analyses evidenced differences between the chemical compositions of the two series of samples likely tied to the synthesis method employed and suggesting off-stoichiometry on the Sb site. High-temperature PXRD and differential scanning calorimetry measurements indicate that these materials are stable up to 623 K. Above this temperature, the decomposition process starts and ends up near 748 K where a Cu2-yS-type phase is solely observed. In agreement with the simple electron counting rule and electronic band structure calculations, the electrical resistivity and thermopower increase with increasing x reflecting the gradual shift from a p-type metallic state (x = 0.0) to a p-type semiconducting behavior (x = 2.0). Combined with extremely low lattice thermal conductivity values (kappa approximate to 0.5 W m(-1) K-1 at 623 K), this substitution enables us to optimize the power factor leading to a maximum thermoelectric figure of merit ZT of about 0.8 at 623 K. These results parallel those obtained in prior studies dealing with partial substitutions on the Cu site and enlarge the possibilities to tune the electrical properties of tetrahedrites by extrinsic dopants.
