Szczegóły publikacji

Opis bibliograficzny

Studies on $N-vinylformamide$ cross-linked copolymers / Joanna Świder, Agnieszka TĄTA, Katarzyna Sokołowska, Ewa Witek, Edyta PRONIEWICZ // Journal of Molecular Structure ; ISSN 0022-2860. — 2015 — vol. 1102, s. 42–49. — Bibliogr. s. 48–49, Abstr.

Autorzy (5)

Słowa kluczowe

FTIRthree dimensional free radical polymerization in inverse suspensionFT-RamanFourier transform absorption infrared spectroscopyN-vinylformamide cross-linked copolymersNVF

Dane bibliometryczne

ID BaDAP91567
Data dodania do BaDAP2015-09-28
Tekst źródłowyURL
DOI10.1016/j.molstruc.2015.08.039
Rok publikacji2015
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaJournal of Molecular Structure

Abstract

Copolymers of N-vinylformamide (NW) cross-linked with three multifunctional monomers, including divinylbenzene (DVB), ethylene glycol dimethacrylate (EGDMA), and N,N'-methylenebisacrylamide (MBA) were synthetized by a three-dimensional free radical polymerization in inverse suspension using 2,2'-azobis(2-methylpropionamide) dihydrochloride (AIBA) as an initiator. Methyl silicon oil was used as the continuous phase during the polymerization processes. Fourier-transform adsorption infrared (FT-IR) spectra revealed the presence of silicone oil traces and suggested that silicone oil strongly interacted with the copolymers surface. Purification procedure allowed to completely remove the silicon oil traces from P(NVF-co-DVB) only. The morphology and the structure of the investigated copolymers were examined by optical microscopy, FT-IR, and FT-Raman (Fourier-transform Raman spectroscopy) methods. (C) 2015 Elsevier B.V. All rights reserved.

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