Szczegóły publikacji
Opis bibliograficzny
Influence of $Sn_{Bi}$ antisite defects on the electronic band structure and transport properties of the layered chalcogenide semiconductor $SnBi_{2}Te_{4}$ / Ilayda Terzi, Kacper PRYGA, Bartłomiej WIENDLOCHA, Petr Levinský, Soufiane El Oualid, Sylvie Migot, Jaafar Ghanbaja, Christine Gendarme, Thierry Schweitzer, Bernard Malaman, Gérard Le Caër, Bertrand Lenoir, Christophe Candolfi // Journal of Physical Chemistry. C ; ISSN 1932-7447. — 2024 — vol. 128 iss. 44, s. 18976–18992. — Bibliogr. s. 18990–18992, Abstr. — Publikacja dostępna online od: 2024-10-25
Autorzy (13)
- Terzi Ilayda
- AGHPryga Kacper
- AGHWiendlocha Bartłomiej
- Levinský Petr
- El Oualid Soufiane
- Migot Sylvie
- Ghanbaja Jaafar
- Gendarme Christine
- Schweitzer Thierry
- Malaman Bernard
- Le Caër Gérard
- Lenoir Bertrand
- Candolfi Christophe
Dane bibliometryczne
| ID BaDAP | 156624 |
|---|---|
| Data dodania do BaDAP | 2024-12-18 |
| Tekst źródłowy | URL |
| DOI | 10.1021/acs.jpcc.4c06097 |
| Rok publikacji | 2024 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Journal of Physical Chemistry, C |
Abstract
Narrow-band gap, layered chalcogenide semiconductors provide a rich area of research for designing highly efficient thermoelectric materials for near-room-temperature applications due to their intrinsically low lattice thermal conductivity and multivalley electronic band structure. Here, we report on a comprehensive theoretical and experimental investigation of the thermoelectric properties of one member of this class, SnBi2Te4, in the temperature range of 5–700 K. Polycrystalline samples crystallize with a rhombohedral crystal structure described in the R3̅m space group (No. 166) with room-temperature lattice parameters a = 4.398(1) and c = 41.615(1) Å. To probe the electronic tunability of SnBi2Te4, the synthesis of a Sn-deficient sample Sn0.95Bi2Te4 was attempted but led to an intergrowth of SnBi2Te4 and SnBi4Te7, indicating that only a very limited range of Sn-deficiency can exist. Transport property measurements combined with electronic band structure calculations show that SnBi2Te4 is a p-type, narrow-band gap semiconductor with a multivalley valence band structure and a strong asymmetry between the valence and conduction bands. The presence of SnBi antisite defects, supported by Mössbauer spectroscopy, plays an important role in shaping the electronic transport properties through a decrease in the electronic band gap and a reduction in the hole mobility, which causes the onset of bipolar conduction near 350 K. Some degree of anisotropy in the electrical resistivity and thermal conductivity measured parallel and perpendicular to the pressing direction exists, while the thermopower remains nearly isotropic. The complex crystal structure of SnBi2Te4 contributes to the very low lattice thermal conductivity of the order of 0.5 W m–1 K–1 at 300 K, leading to peak ZT values of 0.32 at 350 and 400 K for Sn0.95Bi2Te4 and SnBi2Te4, respectively.
