Szczegóły publikacji

Opis bibliograficzny

A critical investigation of the effect of silver migration at the silver | alumina scandia doped zirconia electrolyte interface in solid oxide fuel cell conditions / Amir Sultan, Muhammad Bilal Hanif, Muhammad Zubair Khan, Kun ZHENG, Magdalena DUDEK, Bogna Daria Napruszewska, Wieslaw Lasocha, Pawel Nowak, Martin Motola // Ceramics International ; ISSN  0272-8842 . — Tytuł poprz.: Ceramurgia International ; ISSN:  0390-5519. — 2024 — vol. 50 iss. 21 pt. B, s. 42656-42667. — Bibliogr. s. 42666-42667, Abstr. — Publikacja dostępna online od: 2024-08-10. — K. Zheng - dod. afiliacja: AGH Centre of Energy ; A. Sultan - afiliacja: Polish Academy of Science

Autorzy (9)

Słowa kluczowe

electrode potentialimpedance spectroscopysolid oxide fuel cellssilverelectromigrationalumina scandia doped zirconia electrolytes

Dane bibliometryczne

ID BaDAP155742
Data dodania do BaDAP2024-10-25
Tekst źródłowyURL
DOI10.1016/j.ceramint.2024.08.109
Rok publikacji2024
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaCeramics International

Abstract

In this work, a critical evaluation of silver ion migration at the surface of Al0.04Sc0.06Zr0.9O1.95 (AlScZrO) electrolyte is explored in intermediate temperature solid oxide fuel cells (IT-SOFCs). The behaviour of silver is systematically studied at the operating conditions of silver as a cathode, anode, or sealant in IT-SOFCs. The results to those obtained at the surface of other electrolytes (gadolinia doped ceria, samaria doped ceria and yttria-stabilized zirconia) are also analysed. In the case of cathodic polarization, a thick silver deposit is formed around the electrode on the surface of the electrolyte, which may lead to the short-circuiting of the electrodes. While for the anodic polarization, oxygen bubbles are formed between the electrode and electrolyte, leading the delamination of electrode. Silver can also migrate from unpolarized parts of the cell such as sealants. Therefore, Issues related to the application of silver in IT-SOFCs should be concerned by the scientific community.

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