Szczegóły publikacji

Opis bibliograficzny

Long-time evaluation of solid-state composite reference electrodes / Slim Blidi, Kim Granholm, Tomasz Sokalski, Zekra Mousavi, Andrzej LEWENSTAM, Ivo Leito, Johan Bobacka // Membranes [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 2077-0375. — 2022 — vol. 12 iss. 6 art. no.  569, s. 1-11. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 10-11, Abstr. — Publikacja dostępna online od: 2022-05-30. — A. Lewenstam - dod. afiliacja: Åbo Akademi University, Finland


Autorzy (7)


Słowa kluczowe

reference electrodesolid statelong-time evaluation

Dane bibliometryczne

ID BaDAP141438
Data dodania do BaDAP2022-08-16
Tekst źródłowyURL
DOI10.3390/membranes12060569
Rok publikacji2022
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaMembranes

Abstract

In this study, the performance and long-time evaluation of solid-state composite (SSC) reference electrodes were investigated. The stability of all the SSC reference electrodes was continuously monitored by using potentiometry and electrochemical impedance spectroscopy methods over a period of several months. A multi-solution protocol was used to study the influence of the ionic strength of the sample solution, ion charge, and mobility, and the sample pH values on the performance of the reference electrodes. The SSC reference electrodes were used in the calibration of commercial indicator electrodes for different ions at different temperatures. The concentrations of K+, Na+, Ca2+, and Cl- ions and pH values were measured in river water samples at different temperatures using the SSC reference electrodes. The obtained results for the same samples were compared with the results given by an independent laboratory specialized in routine water analyses. The agreement between the results was very good and even better than the case where commercial reference electrodes were used. Our study showed that the SSC reference electrodes exhibit good long-term stability and excellent performance, both in the calibrations and analyses of environmental samples.

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