Szczegóły publikacji

Opis bibliograficzny

Reference electrodes with polymer-based membranes – comprehensive performance characteristics / Peter Lingenfelter, Bartosz BARTOSZEWICZ, Jan MIGDALSKI, Tomasz Sokalski, Mirosław M. BUĆKO, Robert FILIPEK, Andrzej LEWENSTAM // Membranes [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 2077-0375. — 2019 — vol. 9 iss. 12 art. no. 161, s. 1–22. — Bibliogr. s. 18–22, Abstr. — Publikacja dostępna online od: 2019-11-29


Autorzy (7)


Słowa kluczowe

polymer membranesreference electrodeheterogenous membranespotentiometrysolid contact

Dane bibliometryczne

ID BaDAP126377
Data dodania do BaDAP2020-01-07
Tekst źródłowyURL
DOI10.3390/membranes9120161
Rok publikacji2019
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaMembranes

Abstract

Several types of liquid membrane and solid-state reference electrodes based on different plastics were fabricated. In the membranes studied, equitransferent organic (QB) and inorganic salts (KCl) are dispersed in polyvinyl chloride (PVC), polyurethane (PU), urea-formaldehyde resin (UF), polyvinyl acetate (PVA), as well as remelted KCl in order to show the matrix impact on the reference membranes’ behavior. The comparison of potentiometic performance was made using specially designed standardized testing protocols. A problem in the reference electrode research and literature has been a lack of standardized testing, which leads to difficulties in comparing different types, qualities, and properties of reference electrodes. Herein, several protocols were developed to test the electrodes’ performance with respect to stability over time, pH sensitivity, ionic strength, and various ionic species. All of the prepared reference electrodes performed well in at least some respect and would be suitable for certain applications as described in the text. Most of the reference types, however, demonstrated some weakness that had not been previously highlighted in the literature, due in large part to the lack of exhaustive and/or consistent testing protocols. © 2019 by the authors. Licensee MDPI, Basel, Switzerland.

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