Szczegóły publikacji

Opis bibliograficzny

A Raman spectroscopic analysis of polymer membranes with graphene oxide and reduced graphene oxide / Anna Kołodziej, Elżbieta DŁUGOŃ, Małgorzata Świętek, Magdalena ZIĄBKA, Emilia Dawiec, Maciej GUBERNAT, Marek Michalec, Aleksandra Wesełucha-Birczyńska // Journal of Composites Science [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 2504-477X. — 2021 — vol.5 iss. 1 art. no. 20, s. 1–14. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 12–14, Abstr. — Publikacja dostępna online od: 2021-01-08

Autorzy (8)

Słowa kluczowe

reduced graphene oxideGOgraphene oxideRaman microspectroscopyrGOpoly(epsilon-caprolactone)polymer nanocomposite

Dane bibliometryczne

ID BaDAP132055
Data dodania do BaDAP2021-01-11
Tekst źródłowyURL
DOI10.3390/jcs5010020
Rok publikacji2021
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaJournal of Composites Science

Abstract

Nowadays, despite significant advances in the field of biomaterials for tissue engineering applications, novel bone substituents still need refinement so they can be successfully implemented into the medical treatment of bone fractures. Generally, a scaffold made of synthetic polymer blended with nanofillers was proven to be a very promising biomaterial for tissue engineering, however the choice of components for the said scaffold remains questionable. The objects of the presented study were novel composites consisting of poly(epsilon-caprolactone) (PCL) and two types of graphene materials: graphene oxide (GO) and partially reduced graphene oxide (rGO). The technique of choice, that was used to characterize the obtained composites, was Raman micro-spectroscopy. It revealed that the composite PCL/GO differs substantially from the PCL/rGO composite. The incorporation of the GO particles into the polymer influenced the structure organisation of the polymeric matrix more significantly than rGO. The crystallinity parameters confirmed that the level of crystallinity is generally higher in the PCL/GO membrane in comparison to PCL/rGO (and even in raw PCL) that leads to the conclusion that the GO acts as a nucleation agent enhancing the crystallization of PCL. Interestingly, the characteristics of the studied nanofillers, for example: the level of the organisation (D/G ratio) and the in-plane size of the nano-crystallites (L-a) almost do not differ. However, they have an ability to influence polymeric matrix differently.

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