Szczegóły publikacji
Opis bibliograficzny
Kinetic studies of Pt(IV) chloride complex ions reduction reaction using potassium formate / M. WOJNICKI, P. ŻABIŃSKI, Edit Csapó // Archives of Metallurgy and Materials / Polish Academy of Sciences. Committee of Metallurgy. Institute of Metallurgy and Materials Science ; ISSN 1733-3490. — 2020 — vol. 65 iss. 3, s. 1135–1140. — Bibliogr. s. 1140
Autorzy (3)
- AGHWojnicki Marek
- AGHŻabiński Piotr
- Csapó Edit
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 129075 |
|---|---|
| Data dodania do BaDAP | 2020-06-19 |
| Tekst źródłowy | URL |
| DOI | 10.24425/amm.2020.133230 |
| Rok publikacji | 2020 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Creative Commons | |
| Czasopismo/seria | Archives of Metallurgy and Materials |
Abstract
In this paper, the kinetics of the platinum(IV) chloride complex ions reduction reaction was studied. It was shown that the mechanism exhibits autocatalytic character. The presence of metallic platinum in the system significantly increases the reaction rate. The influence of the initial concentration of precursor, reductant, ionic strength, initial concentration of the chloride ions as well as the temperature on the process rate was investigated. The activation energy was determined and is equal to 93.57 kJ/mol. Moreover, the obtained metallic phase was analyzed, and it was observed that it has a micrometric size.
