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Opis bibliograficzny
A- and B-site doping effect on physicochemical properties of $Sr_{2−x}Ba_{x}MMoO_{6}$ (M = Mg, Mn, Fe) double perovskites — candidate anode materials for SOFCs / Kun ZHENG, Konrad ŚWIERCZEK // Functional Materials Letters ; ISSN 1793-6047. — 2016 — vol. 9 no. 4, s. 1641002-1–1641002-4. — Bibliogr. s. 1641002-4
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| ID BaDAP | 99529 |
|---|---|
| Data dodania do BaDAP | 2016-08-25 |
| DOI | 10.1142/S1793604716410022 |
| Rok publikacji | 2016 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp | |
| Czasopismo/seria | Functional Materials Letters |
Abstract
In this work, we evaluate the physicochemical properties of Sr2-xBaxMMoO6 (M = Mg, Mn, Fe) double perovskites as alternative anode materials for solid oxide fuel cells, for which the effect of substitution of strontium by barium in a full range of compositions is studied. The crystal structure, microstructure, characterization of transport properties (electrical conductivity, Seebeck coefficient) and oxygen content as a function of temperature, as well as chemical stability in oxidizing and reducing conditions are discussed. Fe-and Mo-containing Sr2-xBaxMMoO6 oxides show very high total conductivities with values of 100-1000 S·cm-1, while Sr2-xBaxMMoO6 present good redox stability. © 2016 World Scientific Publishing Company.