Szczegóły publikacji
Opis bibliograficzny
Improvement of electrochemical performance of $Na_{0.7}Co_{1-y}Mn_{y}O_{2}$–cathode material for rechargeable sodium-ion batteries / Dominika BASTER, Wojciech ZAJĄC, Łukasz KONDRACKI, Filip HARTMAN, Janina MOLENDA // Solid State Ionics ; ISSN 0167-2738. — 2016 — vol. 288, s. 213–218. — Bibliogr. s. 217–218, Abstr. — Publikacja dostępna online od: 2016-01-19. — SSI-20 : 20th international conference on Solid State Ionics : Keystone, Colorado, USA, June 14–19th 2015
Autorzy (5)
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 97994 |
|---|---|
| Data dodania do BaDAP | 2016-06-11 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.ssi.2016.01.003 |
| Rok publikacji | 2016 |
| Typ publikacji | referat w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Solid State Ionics |
Abstract
In this work series of Na0.7Co1 − yMnyO2 (y = 0, 0.2, 0.3, 0.4, 0.6, 0.8) cathode materials were studied in terms of their structural, transport and electrochemical properties in Na/Na+/Na0.7Co1 − yMnyO2 cells. The materials were synthesized by a high-temperature solid-state reaction. XRD measurements with Rietveld analysis confirmed presence of a single phase with P63/mmc symmetry for all the obtained compositions, except for Na0.7Co0.6Mn0.4O2. Electrical conductivity shows metallic-type character for NaxCoO2 (x ≈ 0.7) and activated character for sodium cobaltate substituted with manganese. Electrical conductivity decreases with the increase of manganese content. Electrochemical studies performed for Na/Na+/Na0.7 + xCo1 − yMnyO2 revealed changes in the character of discharge curve after replacement of Co ions with Mn ions. The most promising electrochemical performance was achieved for Na0.7Co0.7Mn0.3O2. Comprehensive studies of selected Na0.7Co0.7Mn0.3O2 composition (structural properties, discharge capacity at different current rates, cyclic voltammetry and impedance characteristic of cells) were conducted.
