Szczegóły publikacji

Opis bibliograficzny

Wetting hierarchy in oleophobic 3D electrospun nanofiber networks / Urszula STACHEWICZ, Russell J. Bailey, Hao Zhang, Corinne A. Stone, Colin R. Willis, Asa H. Barber // ACS Applied Materials & Interfaces ; ISSN 1944-8244. — 2015 — vol. 7 iss. 30, s. 16645–16652. — Bibliogr. s. 16651–16652, Abstr. — E. Stachewicz – dod. afiliacja: Nanoforce Technology Ltd. ; Queen Mary University of London

Autorzy (6)

Słowa kluczowe

cryo-SEMFIB SEM tomographyelectrospinningwettingpolymeric nanofiber

Dane bibliometryczne

ID BaDAP91818
Data dodania do BaDAP2015-10-06
DOI10.1021/acsami.5b04272
Rok publikacji2015
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaACS Applied Materials & Interfaces

Abstract

Wetting behavior between electrospun nanofibrous networks and liquids is of critical importance in many applications including filtration and liquid-repellent textiles. The relationship between intrinsic nanofiber properties, including surface characteristics, and extrinsic nanofibrous network organization on resultant wetting characteristics of the nanofiber network is shown in this work. Novel 3D imaging exploiting focused ion beam (FIB) microscopy and cryo-scanning electron microscopy (cryo-SEM) highlights a wetting hierarchy that defines liquid interactions with the network. Specifically, small length scale partial wetting between individual electrospun nanofibers and low surface tension liquids, measured both using direct SEM visualization and a nano Wilhelmy balance approach, provides oleophobic surfaces due to the high porosity of electrospun nanofiber networks. These observations conform to a metastable Cassie-Baxter regime and are important in defining general rules for understanding the wetting behavior between fibrous solids and low surface tension liquids for omniphobic functionality.

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