Szczegóły publikacji
Opis bibliograficzny
FTIR spectroscopic investigations of polyaniline derivatives-palladium systems / M. HASIK, A. Drelinkiewicz, E. Wenda, C. PALUSZKIEWICZ, S. Quillard // Journal of Molecular Structure ; ISSN 0022-2860. — 2001 — vol. 596 iss. 1–3, s. 89–99. — Bibliogr. s. 98–99, Abstr. — 3rd International Conference of the Vibrational Spectroscopy in Materials Science : Kraków, SEP 23-26, 2000
Autorzy (5)
- AGHHasik Magdalena
- Drelinkiewicz A.
- Wenda Elżbieta
- AGHPaluszkiewicz Czesława
- Quillard S.
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 7565 |
|---|---|
| Data dodania do BaDAP | 2002-01-21 |
| Tekst źródłowy | URL |
| DOI | 10.1016/S0022-2860(01)00694-9 |
| Rok publikacji | 2001 |
| Typ publikacji | referat w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Journal of Molecular Structure |
Abstract
Ring-substituted polyaniline derivatives: poly(o-toluidine) (POT) and poly(o-chloroaniline) (POC) have been treated with PdCl2 solutions in 0.1 and 1 M HCL Polymer-palladium systems thus obtained have been studied by vibrational spectroscopic methods (MIR, FIR, Raman) and chemical analysis. Results have been compared with those obtained for unsubstituted polyaniline (PANI)-palladium systems prepared under similar experimental conditions as well as for POT, POC, PANI treated with 0.1 and I M HCl. It has been found that in all the cases polymers are protonated. Substitution of one hydrogen atom in PANI ring with -Cl and -CH3 influences the basic and redox properties of the parent polymer The lowest reactivity towards palladium ions has been observed in the case of POC.
