Szczegóły publikacji

Opis bibliograficzny

On the kinetics of the $\alpha-\sigma$ phase transformation in an $Al-doped Fe-Cr$ alloy / A. BŁACHOWSKI, S. M. DUBIEL, J. ŻUKROWSKI, J. CIEŚLAK, B. Sepiol // Journal of Alloys and Compounds ; ISSN 0925-8388. — 2000 — vol. 313 iss. 1–2, s. 182–187. — Bibliogr. s. 186–187, Abstr. — Publikacja dostępna online od: 2000-12-04

Autorzy (5)

Słowa kluczowe

Mossbauer spectroscopytransition metal alloysphase transformation

Dane bibliometryczne

ID BaDAP7324
Data dodania do BaDAP2002-01-07
Tekst źródłowyURL
DOI10.1016/S0925-8388(00)01139-7
Rok publikacji2000
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaJournal of Alloys and Compounds

Abstract

The influence of aluminium on the kinetics of the sigma -phase formation in a quasi-equiatomic Fe-Cr alloy with fine- and coarse-grained structure was studied using Fe-57 Mossbauer Spectroscopy. The amount of the sigma -phase precipitated could be well described by use of the Johnson-Avrami-Mehl equation which yielded the kinetics parameters k and it. Assuming the k-values follow the Arrhenius law, the effective activation energy, E, was determined. It was found that addition of 0.2 at% Al slightly accelerated the kinetics in the coarse-grained samples (E smaller by similar to 1.7 kJ mol(-1)), and practically did not affect it in the fine-grained samples. On the other hand, doping with 1 at%: Al resulted in a significant retardation of the sigma -phase formation both in the fine-grained samples tan increase of E by similar to 16.5 kJ mol(-1)) as well as in the coarse-grained samples (E enhanced by similar to 20.6 kJ mol(-1)). The presence of Al also affected the value of the form factor, II, hence the underlying mechanisms responsible for the transformation. (C) 2000 Elsevier Science B.V. All rights reserved.

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