Szczegóły publikacji

Opis bibliograficzny

A model of bi-functional zirconia / Tadeusz Bąk, Janusz Nowotny, Mieczysław RĘKAS, Charles C. Sorrell // Bulletin of the Polish Academy of Sciences. Chemistry ; ISSN 0239-7285. — 2001 — vol. 49 no. 1, s. 57–65. — Bibliogr. s. 65, Summ.

Autorzy (4)

Słowa kluczowe

defect chemistryzirconiasegregation

Dane bibliometryczne

ID BaDAP5428
Data dodania do BaDAP2001-06-18
Rok publikacji2001
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaBulletin of the Polish Academy of Sciences, Chemistry

Abstract

The paper considers an effect of the gas/solid interface on performance of solid oxide fuel cells (SOFC's). Specifically, application of bi-functional zirconia, involving the functions of a solid electrolyte and electrodes, is outlined. A model, describing the effect of segregation on the formation of a bi-dimensional surface layer, is proposed. The model is considered in terms of the effect of the surface layer on the transfer of charge and matter at the oxygen/zirconia interface. Impact of surface processing of zirconia, involving incorporation of aliovalent ions into the surface layer, on the formation of the bi-functional zirconia is discussed. Application of the bi-functional zirconia for construction of a new generation of electrodeless electrochemical devices is discussed.

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