Szczegóły publikacji
Opis bibliograficzny
Synthesis and spectroscopic properties of porphyrin derivatives of C60 / M. Prato, C. Soombar, E. Vazquez, J. NIZIOŁ, E. Gondek, I. Rau, F. Kajzar // Molecular Crystals and Liquid Crystals ; ISSN 1542-1406 . — 2010 — vol. 521, s. 253–264. — Bibliogr. s. 263–264
Autorzy (7)
- Prato M.
- Soombar C.
- Vazquez E.
- AGHNizioł Jacek
- Gondek Ewa
- Rau Ileana
- Kajzar Francois
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 52777 |
|---|---|
| Data dodania do BaDAP | 2010-08-16 |
| DOI | 10.1080/15421401003726907 |
| Rok publikacji | 2010 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Molecular Crystals and Liquid Crystals |
Abstract
Chemical synthesis of two C60 fullerene derivatives: with porphyrin (C 60-H2P) and of the iodide salt of Zn porphyrin (C 60-H2P)+I- is described. Both compounds are soluble in several organic solvents, with a larger solubility observed for C60-H2P. Thin films obtained by solution drawing or by spinning techniques from C60-H2P solution in organic solvents or dissolved in a polymer matrix show a peculiar granular structure with regular submicron size particles. Their size of is a little smaller in polymer matrix. The solution UV-Vis absorption spectra exhibit typical bands which can be attributed to porphyrin and to the fullerene. A solvatochromic effect is observed in C 60-H2P which shows a nonzero first hyperpolarizability , most likely due to the charge transfer between fullerene and porphyrin. Copyright © Taylor & Francis Group, LLC.
