Szczegóły publikacji
Opis bibliograficzny
A study of the interaction between perylene and the $TiO_{2}(110)-(1\times1)$ surface-based on XPS, UPS and NEXAFS measurements / Jens Bæk Simonsen, Bartosz HANDKE, Zheshen Li, Preben Juul Møller // Surface Science ; ISSN 0039-6028 . — 2009 — vol. 603 iss. 9, s. 1270–1275. — Bibliogr. s. 1275, Abstr.
Autorzy (4)
- Simonsen Jens Bæk
- AGHHandke Bartosz
- Li Zheshen
- Moller Preben Juul
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 51131 |
|---|---|
| Data dodania do BaDAP | 2010-03-25 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.susc.2009.03.016 |
| Rok publikacji | 2009 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Surface Science |
Abstract
The interaction between a semi-large aromatic hydrocarbon compound (perylene) and the TiO2(1 1 0)-(1 × 1) surface under ultra high vacuum conditions has been probed by X-ray photoemission spectroscopy (XPS), ultraviolet photoemission spectroscopy (UPS) and near-edge X-ray absorption fine structure (NEXAFS) methods. UPS measurements of the adsorbate system have been compared with an experimental UPS spectrum of perylene in the gas phase and a calculated spectrum obtained by means of density functional theory (DFT) methods. NEXAFS results of perylene molecules adsorbed on TiO2(1 1 0)-(1 × 1) were compared with data from an α-phase perylene single crystal. A novel analysis of the valence data has been employed to show that no strong chemical interaction takes place between perylene and the TiO2(1 1 0)-(1 × 1) surface. Furthermore, angle-dependent NEXAFS measurements and the growth curve results suggest that the perylene molecules are oriented flat down onto the TiO2 substrate due to weak van der Waals interactions.
