Szczegóły publikacji
Opis bibliograficzny
Formation of ${N_{2}O}$ during thermal decomposition of d-metal hydrates nitrates / Andrzej MAŁECKI, Barbara MAŁECKA // Thermochimica Acta ; ISSN 0040-6031 . — 2006 — vol. 446 iss. 1–2, spec. iss., s. 113–116. — Bibliogr. s. 116, Abstr.
Autorzy (2)
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 30563 |
|---|---|
| Data dodania do BaDAP | 2006-12-11 |
| DOI | 10.1016/j.tca.2006.02.006 |
| Rok publikacji | 2006 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Thermochimica Acta |
Abstract
It was found that during thermal decomposition of hydrates of d-metal nitrates nitrous oxide (N2O) is always present among the other gaseous products: H2O, HNO3, NO, NO2 and O-2. In all studied decomposition reactions the nitrous oxide formed contains approximately 5-8%, of total nitrogen coming from nitrate. Two new mechanisms of NO formation, based on the reaction between NO or NO2 and nitrate ion. have been proposed. The discussed third possible mechanism: (a) 2NO=N2O2 and (b) N2O2+NO=N2O+NO2 is unlikely. (c) 2006 Elsevier B.V. All rights reserved.
