Szczegóły publikacji

Opis bibliograficzny

Infrared studies of glasses in the $Li_{2}O-B_{2}O_{3}-GeO_{2}(SiO_{2})$ systems / K. BŁASZCZAK, W. Jelonek, A. ADAMCZYK // Journal of Molecular Structure ; ISSN 0022-2860. — 1999 — vol. 511–512, s. 163–166. — Bibliogr. s. 166, Abstr. — Vibrational Spectroscopy in Materials Science : proceedings of an International Conference, Kraków, Poland, 22–25 October 1998

Autorzy (3)

Słowa kluczowe

infrared spectroscopyLi2O-B2O3-GeO2 (SiO2) glassesglass structure

Dane bibliometryczne

ID BaDAP2811
Data dodania do BaDAP2001-04-18
Tekst źródłowyURL
DOI10.1016/S0022-2860(99)00155-6
Rok publikacji1999
Typ publikacjireferat w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaJournal of Molecular Structure

Abstract

Glasses of composition according to the formula Li2O . B2O3. xGeO(2)(SiO2) where x = 1,2 and 4 (number of GeO2 or SiO2 moles) were synthesised. Spectroscopic studies in the middle infrared range of 1800-400 cm(-1) were carried out. Interpretation of the obtained vibrational spectra allows us to make some conclusions on the structure of the studied glasses: they are built up of [GeO4] or [SiO4] tetrahedra and also [BO3] triangles and [BO4] tetrahedra. In such glasses of mixed framework, the lithium ion does not act as depolymerisator but stabilizes the tetrahedrally coordinated boron.

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Infrared studies of devitrification of glasses in the $Li_{2}O-B_{2}O_{3}-GeO_{2}$ system / K. BŁASZCZAK, A. ADAMCZYK // Journal of Molecular Structure ; ISSN 0022-2860. — 2001 — vol. 596 iss. 1–3, s. 61–68. — Bibliogr. s. 68, Abstr.
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