Szczegóły publikacji
Opis bibliograficzny
RAMAN, FTIR and PXRD studies of water in cinchoninum tetrachlorocadmate(II) hemipentahydrate and tetrachlorozincate(II) dihydrate compounds / A. Wesełucha-Birczyńska, C. Paluszkiewicz, B. Borzecka-Prokop // Journal of Molecular Structure ; ISSN 0022-2860. — 2005 — vols. 744–747, s. 839–844. — Bibliogr. s. 844, Abstr. — Publikacja dostępna online od: 2005-03-02. — C. Paluszkiewicz - afiliacja: Jagiellonian University. — Molecular spectroscopy and molecular structure 2004 : a collection of papers presented at the XXVIIth European congress on Molecular spectroscopy : Kraków, Poland, September 5–10, 2004 / eds. A. J. Barnes, M. Handke, C. Paluszkiewicz, H. Ratajczak. — [S. l.] : Elsevier, 2005
Autorzy (3)
- Wesełucha-Birczyńska A.
- Paluszkiewicz Czesława
- Borzęcka-Prokop B.
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 27020 |
|---|---|
| Data dodania do BaDAP | 2006-03-31 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.molstruc.2005.01.033 |
| Rok publikacji | 2005 |
| Typ publikacji | referat w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Journal of Molecular Structure |
Abstract
Two transition metal (Cd(II) and Zn(II)) compounds with cinchonine, i.e. [(cinH(2))CdCl4](.)2.5H(2)O and [(cinH2)ZnCl4](.)2H(2)O were studied, to explain the role of water molecules contained in their structure. FT-Raman and MR spectroscopy along with powder X-ray diffraction (PXRD) methods were applied to analyse structural changes induced in Zn(II) and Cd(II) derivatives by: (i) loosing crystallisation water as well as (ii) lowering temperature to 10 K. The PXRD patterns point to stronger changes in Cd(II)-cin structure framework on heating, confirmed by appearance of new reflections at low angle region. This fact may suggest differences in water bonding in Zn(II)-cin and Cd(II)-cin compounds. FT-Raman spectroscopy allow to indicate bands which characterise vibrations in which water molecules are involved, i.e. 1606 cm(-1) and also to those which are disturbed by disappearance of the water, i.e. 3120, 3 100 and 3077 cm(-1). Redistribution of relative intensities in 1350-1400 cm(-1) region, was a confirmation that Cd(II)-cin structure with doubly protonated cinchonine at N1 and N13 is a stable form. The observed changes in MIR spectra seem to be connected with the rearrangement of the hydrogen bond network and with the reorganisation of the cinchonine constituent moieties as a function of temperature. (c) 2005 Elsevier B.V. All rights reserved.
