Szczegóły publikacji
Opis bibliograficzny
The role of synthesis parameters in preparation of Cu,Cr-layered double hydroxides / A. Michalik, A. Pacuła, E. M. Serwicka, K. BAHRANOWSKI, A. GAWEŁ, R. Dziembaj, E. Bielańska // Polish Journal of Chemistry / Polish Academy of Sciences. Committee of Chemistry, Polish Chemical Society ; ISSN 0137-5083 . — Tytuł poprz.: Roczniki Chemii. — 2004 — vol. 78 iss. 11–12, s. 1997–2004. — Bibliogr. s. 2004
Autorzy (7)
- Michalik A.
- Pacuła Aleksandra
- Serwicka-Bahranowska Ewa Maria
- AGHBahranowski Krzysztof
- AGHGaweł Adam
- Dziembaj R.
- Bielańska Elżbieta
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 23148 |
|---|---|
| Data dodania do BaDAP | 2005-09-09 |
| Rok publikacji | 2004 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Polish Journal of Chemistry |
Abstract
A series of Cu,Cr-layered double hydroxides of Cu/Cr ratio equal 2 has been synthesized by co-precipitation at a constant pH, using different preparative conditions. The investigated synthesis parameters included: ageing time, speed of reactants addition, temperature of co-precipitation and pH of synthesis. The dominant product of the synthesis was the nitrate form of Cu,Cr-LDH, containing ca. 10 mol% of carbonate. Modifications of experimental conditions affected chiefly the samples crystallinity. The most obvious effects were associated with changing of pH of the co-precipitation, the most acidic conditions providing a material of the best crystallinity. At the medium synthesis temperature (55degreesC), a slow addition of the reactants and a long ageing were favourable, but a significant shortening of the ageing time caused only minor deterioration of the sample crystallinity. The latter finding is of practical importance for an upscaling of the process.
