Szczegóły publikacji

Opis bibliograficzny

Defect-diffusion-stress relationships in modeling the oxidation and degradation processes of alumina formers : a brief survey / J. JEDLIŃSKI // Diffusion and Defect Data – Solid State Data . Part A, Defect and Diffusion Forum ; ISSN  1012-0386. — 2005 — vols. 237–240 Pt. 2, s. 911–921. — Bibliogr. s. 919–921, Abstr. — DIMAT 2004 : Diffusion in Materials : proceedings of the 6th international conference on Diffusion in Materials : Cracow, Poland, July 18–23, 2004 / eds. M. Danielewski [et al.]. — Uetikon-Zuerich, Switzerland : TTP Trans Tech Publications Ltd., 2005

Autor

Słowa kluczowe

high temperature degradationhigh temperature oxidationalumina formers

Dane bibliometryczne

ID BaDAP22360
Data dodania do BaDAP2005-05-23
Tekst źródłowyURL
DOI10.4028/www.scientific.net/DDF.237-240.911
Rok publikacji2005
Typ publikacjireferat w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaDiffusion and Defect Data. Solid State Data, Part A, Defect and Diffusion Forum

Abstract

In the modeling of the oxidation and degradation processes of the superior metallic materials in terms of the high temperature oxidation resistance, being the so-called alumina formers, the matter transport only via grain boundaries of alpha-Al2O3 is usually taken into account. This paper indicates that such an approach needs to be re-visited. It is pointed out that the following factors should be taken into account (i) diffusion via point defects in the unstable alumina polymorphs (gamma, delta, theta) which grow during the early oxidation stages; (ii) dislocation-related processes; (iii) formation of the oxide in three-dimensional defects, being the cracks in the oxide layer; (iv) outward oxide growth resulting from the formation of the new oxide within the existing layer. The mentioned above effects as well as the other ones, related to the interfacial and stress-induced processes are illustrated and discussed. It is pointed out that alumina formers constitute a wide group of materials and several categories should be distinguished among them with respect to their composition and production route on one hand, and the oxidation and degradation mechanisms, on the other hand. It is shown that the comprehensive approach enables better and self-consistent modeling of the oxidation and degradation mechanisms of alumina formers.

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