Szczegóły publikacji

Opis bibliograficzny

Juglone/MWCNT-modified electrode for high-performance melatonin detection / Joanna SMAJDOR-BARAN // International Journal of Molecular Sciences [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN  1422-0067 . — 2026 — vol. 27 iss. 14 art. no. 6237, s. 1–19. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 16–19, Abstr. — Publikacja dostępna online od: 2026-07-13

Autor

Słowa kluczowe

juglonepaste electrodesmelatoninMWCNTsvoltammetry

Dane bibliometryczne

ID BaDAP169288
Data dodania do BaDAP2026-07-31
Tekst źródłowyURL
DOI10.3390/ijms27146237
Rok publikacji2026
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaInternational Journal of Molecular Sciences

Abstract

The integration of carbon nanomaterials with organic compounds offers a promising strategy for developing next-generation electrode materials with superior properties. A novel type of carbon paste electrode was fabricated by modifying a graphite matrix with functionalized multiwalled carbon nanotubes and juglone as a redox mediator, and then it was deposited by manual packing into a PEEK body (JUG-MWCNT/CPE). The surface morphology and structural parameters of the composite materials were meticulously characterized using scanning electron microscopy (SEM), nitrogen adsorption–desorption isotherms, and spectroscopic techniques, while their electrochemical properties were rigorously evaluated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV). This study demonstrates that the synergistic interaction between the conductive nanotube network and the electroactive juglone significantly reduces the oxidation overpotential and enhances the peak current response of melatonin. Under optimized DPV parameters, the developed sensor presents outstanding analytical performance, featuring a wide linear response range from 0.002 to 0.16 mg L−1, a low detection limit of 0.49 µg L−1, excellent long-term signal stability for up to 30 days, and valid applicability for real-sample monitoring in commercial tablets and dietary supplements.

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