Szczegóły publikacji
Opis bibliograficzny
Bio-based compounds from synergistic processing of bone waste via advanced ultrasound assisted-enzymatic pretreatment and fast pyrolysis / Gabriela Ionescu, Mircea Gabriel Macavei, Mariana Pătrașcu, Agata MLONKA-MĘDRALA, Gabriela Petcu, Szymon Sobek, Aneta MAGDZIARZ, Cosmin Mărculescu // Bioresource Technology ; ISSN 0960-8524 . — 2026 — vol. 455 art. no. 134860, s. 1–12. — Bibliogr. s. 10–12, Abstr. — Publikacja dostępna online od: 2026-05-12
Autorzy (8)
- Ionescu Gabriela
- Macavei Mircea Gabriel
- Pătrașcu Mariana
- AGHMlonka-Mędrala Agata
- Petcu Gabriela
- Sobek Szymon
- AGHMagdziarz Aneta
- Mărculescu Cosmin
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 167894 |
|---|---|
| Data dodania do BaDAP | 2026-06-02 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.biortech.2026.134860 |
| Rok publikacji | 2026 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Creative Commons | |
| Czasopismo/seria | Bioresource Technology |
Abstract
This study investigates the synergistic processing of chicken bone waste through a novel combination of advanced ultrasound-assisted enzymatic pretreatment and fast pyrolysis conditions (500–900 °C, ∼100 °C/min). The higher process temperature inhibits CO2, and promotes ≥ C2, CH4, CO and H2. The pyrolysis gas energetic potential reaches a maximum of 33 MJ/Nm3, thus can serve as biofuel. The bio-oil derived from the pyrolysis of feedstock, whether pretreated by classical or enzymatic methods, yields rich in N-heterocycles. At ≥ 700 °C, bio-oil contains more heterocyclic compounds and hydrocarbons. Pyrolysis of enzymatically pretreated feedstock results in higher concentrations of pyrrole and pyrrolo[1,2-a]pyrazine-1,4-dione, hexahydro, which are valuable for the synthesis of organonitrogen compounds relevant to the agriculture, pharmaceutical and advanced materials industries. The H/C < 0.7 and O/C < 0.28 ratios, together with the phosphorus content, indicated a stable high-quality biochar. The increase of process temperature decreases biochar yield, doubles ash content, promotes density and improves thermal stability. The total heat absorbed increases from 22 kJ (500 °C) to 39 kJ (900 °C), indicating a moderate energy demand for pyrolysis. This synergistic processing promotes sustainable poultry waste management and facilitates the circular utilisation of bio-based, compound-oriented products, for their potential use as renewable gases, green chemicals and functional biochar.
