Szczegóły publikacji

Opis bibliograficzny

Molten salt assisted thermochemical conversion of waste for production of sustainable fuels and chemicals: a review / Rehman Farooq, Cui Quan, Xizhi Cheng, Ye Shui Zhang, Aneta MAGDZIARZ, Ningbo Gao // Biomass & Bioenergy ; ISSN  0961-9534 . — 2026 — vol. 214 art. no. 109469, s. 1-28. — Bibliogr. s. 24-28, Abstr. — Publikacja dostępna online od: 2026-04-25

Autorzy (6)

Słowa kluczowe

hydrogen productionmolten salt assisted pyrolysis and gassificationreactor designcatalytic crackingcarbon materials

Dane bibliometryczne

ID BaDAP167540
Data dodania do BaDAP2026-05-25
Tekst źródłowyURL
DOI10.1016/j.biombioe.2026.109469
Rok publikacji2026
Typ publikacjiprzegląd
Otwarty dostęptak
Czasopismo/seriaBiomass & Bioenergy

Abstract

The growth of industrialization and increasing energy demands worldwide necessitate the use of environmentally friendly alternatives to fossil fuels. Biomass and municipal waste are very rich feedstocks but due to their native moisture content, heterogeneity and low energy content their direct utilization is constrained. Thermochemical conversion of waste in molten-salt offers a promising perspective for transforming biomass and waste into fuels, hydrogen, chemicals and carbon materials utilizing the two distinct properties of high thermal capacity and catalytic ion chemistry. This review discusses recent advances in molten-salt assisted pyrolysis, gasification and oxidation where salt systems (carbonates, chlorides, nitrates, fluorides and eutectics) are compared in terms of their selectivity and operating conditions. The designs of reactors examined with reference to temperature, residence time, and heat/mass transfer behavior. Carbonate salts have been shown to promote deoxygenation and hydrogen production, chloride salts favor cracking and light olefins, fluoride salts have the potential to reduce tar and soot, nitrate salts are capable of promoting partial oxidation and present NOx, and lithium-based compositions promote the graphitization of carbon remains. Among the technical challenges, one may single out corrosion, salt contamination, regeneration, impurity trapping and emissions are important. This review identifies knowledge gaps, including limited pilot-scale demonstrations, salt recovery and recycling, and corrosion of reactor materials. Overall, molten-salt thermochemical approaches have significant potential for sustainable waste valorization provided that engineering and environmental limitations are successfully addressed.

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