Szczegóły publikacji

Opis bibliograficzny

Photocatalytic degradation of methylene blue in aqueous media using magnesium-substituted copper ferrite as a magnetic catalyst / J. MAZURENKO, L. Kaykan, V. Moklyak, M. Petryshyn, O. Mazurenko, S. Leleko // Fìzika ì Hìmìâ Tverdogo Tìla = Physics and Chemistry of Solid State ; ISSN  1729-4428 . — 2024 — vol. 25 no. 3, s. 605–616. — Bibliogr. s. 614–615, Abstr. — Publikacja dostępna online od: 2024-09-23. — J. Mazurenko – dod. afiliacja: Ivano-Frankivsk National Medical University, Ivano-Frankivsk, Ukraine

Autorzy (6)

  • AGHMazurenko Julia
  • Kaykan Larysa S.
  • Moklyak V.
  • Petryshyn Mykhailo
  • Mazurenko Oleksandr
  • Leleko S.

Słowa kluczowe

methylene blueWeibull distribution modelLangmuir-Hinshelwood modecopper nanoferritekinetics fittingphotocatalytic degradation

Dane bibliometryczne

ID BaDAP167283
Data dodania do BaDAP2026-04-29
Tekst źródłowyURL
DOI10.15330/pcss.25.3.605-616
Rok publikacji2024
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaPhysics and Chemistry of Solid State

Abstract

In this study, copper nanosized ferrites substituted with magnesium ions were synthesized using the sol-gel self-combustion method, with polyethylene glycol (MW=2000) W =2000) serving as both fuel and chelating agent. Structural properties were investigated using X-ray diffraction. It was confirmed that all samples crystallized as cubic spinels with space group Fd3m. Optical studies showed band gaps increasing from 1.51 eV for CuFe2O4 2 O 4 to 1.62 eV for MgFe2O4, 2 O 4 , suggesting modifications in electronic structure due to magnesium substitution. Photocatalytic studies revealed that CuFe2O4 2 O 4 exhibited the most efficient degradation of Methylene Blue dye, with near-complete degradation at 160 minutes. Magnesium-substituted samples (x = 0.4 and x = 0.6) also showed significant degradation, though at a slower rate compared to pure CuFe2O4. 2 O 4 . Photocatalytic performance, particularly in degrading Methylene Blue, was evaluated using various kinetic models such as First- and Second-Order Kinetics, the Langmuir-Hinshelwood model, and the two-parameter Weibull distribution.

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