Szczegóły publikacji
Opis bibliograficzny
High-performance, high-entropy perovskite cathodes for low-temperature solid-oxide fuel cells / Juliusz DĄBROWA, Klaudia ZIELIŃSKA, Marek ZAJUSZ, Margarita NOWAKOWSKA, Maria Szymczak, Maciej Moździerz, Andrzej MIKUŁA, Keyun Li, Paweł Czaja, Christian Schwab, Andreas Falkenstein, Manfred Martin, Konrad ŚWIERCZEK // Applied Catalysis . B, Environment and Energy ; ISSN 0926-3373. — 2026 — vol. 391 art. no. 126571, s. 1-16. — Bibliogr. s. 14-16, Abstr. — Publikacja dostępna online od: 2026-02-14. — K. Świerczek - dod. afiliacja: AGH Centre of Energy
Autorzy (13)
- AGHDąbrowa Juliusz
- AGHZielińska Klaudia
- AGHZajusz Marek
- AGHNowakowska Margarita
- AGHSzymczak Maria
- Moździerz Maciej
- AGHMikuła Andrzej
- AGHLi Keyun
- Czaja Paweł
- Schwab Christian
- Falkenstein Andreas
- Martin Manfred
- AGHŚwierczek Konrad
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 167125 |
|---|---|
| Data dodania do BaDAP | 2026-04-29 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.apcatb.2026.126571 |
| Rok publikacji | 2026 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Creative Commons | |
| Czasopismo/seria | Applied Catalysis, B, Environmental |
Abstract
The application of the high-entropy design principle has opened a number of new opportunities in terms of designing superior functional materials. One of the areas which can particularly benefit from that are air-electrodes for solid-oxide fuel cell technology (SOFC), currently suffering from the performance-functionality trade-off, observed in most state-of-the-art materials. In this work, it is demonstrated that careful optimization of La(Co,Cu,Fe,Mn,Ni)O3-δ-based electrodes enables obtaining the performance typical for the low-temperature SOFC operation, with the cathodic polarization resistance Rp values as low as 0.274 Ω cm2 at 600 °C. This excellent value for an alkali-free material is obtained while preserving good thermomechanical behavior, and the chemical stability benefits of the Sr-free composition. The reasons behind this performance are studied both experimentally and theoretically, showing that the presence of Cu in the system is responsible for the reported behavior, introducing synergistic effects outside of the rule-of-mixtures. In general, this study proves the potential of high-entropy approach as a powerful tool for designing SOFC materials, while simultaneously providing design guidelines for other materials to follow.
