Szczegóły publikacji

Opis bibliograficzny

Functional carbonate-hydroxyapatite coatings prepared via plasma electrolytic oxidation process in particles suspension / Vladlens Grebnevs, Maciej Sowa, Marta Wala-Kapica, Viktoriia Korniienko, Kateryna Diedkova, Yuliia Varava, Agata Blacha-Grzechnik, Urszula STACHEWICZ, Joanna KNAPCZYK-KORCZAK, Marcin Basiaga, Agris Berzins, Izabela Matula, Ilona Stabrawa, Aldona Kubala-Kukuś, Grzegorz Dercz, Maksym Pogorielov, Arturs Viksna, Wojciech Simka // Surface and Coatings Technology ; ISSN  0257-8972 . — 2026 — vol. 519 art. no. 132985, s. 1–24. — Bibliogr. s. 19–24, Abstr. — Publikacja dostępna online od: 2025-11-21

Autorzy (18)

  • Grebnevs Vladlens
  • Sowa Maciej
  • Wala-Kapica Marta
  • Korniienko Viktoriia
  • Diedkova Kateryna
  • Varava Yuliia
  • Blacha-Grzechnik Agata
  • AGHStachewicz Urszula
  • AGHKnapczyk-Korczak Joanna
  • Basiaga Marcin
  • Berzins Agris
  • Matula Izabela
  • Stabrawa Ilona
  • Kubala-Kukuś Aldona
  • Dercz Grzegorz
  • Pogorielov Maksym
  • Viksna Arturs
  • Simka Wojciech

Słowa kluczowe

hydroxyapatitecarbonation synthesisbiocompatible coatingsmicro-arc oxidationparticlescalcium carbonateplasma electrolytic oxidation

Dane bibliometryczne

ID BaDAP165056
Data dodania do BaDAP2026-01-22
Tekst źródłowyURL
DOI10.1016/j.surfcoat.2025.132985
Rok publikacji2026
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaSurface & Coatings Technology

Abstract

In this study, composite coatings containing calcium carbonate (CC) and hydroxyapatite (HA) were fabricated on titanium substrate via a novel plasma electrolytic oxidation (PEO) process in particle suspensions. The approach involved synthesizing CC particles via a carbonation route, reacting them with a Na2HPO4 electrolyte, and performing PEO at a limiting voltage of 450 V in the resulting bath. The coatings prepared were similar to 25 mu m thick, porous oxide layers enriched with CC and HA, also containing rutile, anatase, perovskite, and brushite phases. As shown by corrosion tests, particle addition yielded an approximately 16-fold increase in charge transfer resistance and a corrosion potential shift of about 670 mV toward more noble values compared to bare titanium. Scratch testing revealed similar to 30 % higher adhesion and scratch resistance for CC and HA-based coatings. The surfaces were highly biocompatible, bacteriostatic, and hydrophilic, with an initial water contact angle of similar to 30 degrees, decreasing to similar to 10 degrees after 2 min. They exhibited a moderately negative surface zeta potential of -22 mV at pH 7 and demonstrated sustained calcium ion release, reaching similar to 21 mg L-1 under static conditions after 20 days and maintaining similar to 2.5 mg L-1 in PBS under dynamic conditions for 30 days. These results indicate that CC-HA particles significantly enhanced the PEO coatings' functional characteristics, making them promising candidates for next-generation biomedical implants with improved performance.

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