Szczegóły publikacji
Opis bibliograficzny
The influence of various chemical modifications of sheep wool fibers on the long-term mechanical properties of sheep wool/PLA biocomposites / Piotr SZATKOWSKI // Materials [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 1996-1944. — 2025 — vol. 18 iss. 13 art. no. 3056, s. 1–24. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 22–24, Abstr. — Publikacja dostępna online od: 2025-06-27
Autor
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 160979 |
|---|---|
| Data dodania do BaDAP | 2025-07-10 |
| Tekst źródłowy | URL |
| DOI | 10.3390/ma18133056 |
| Rok publikacji | 2025 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Creative Commons | |
| Czasopismo/seria | Materials |
Abstract
Sheep wool is a natural fiber from various sheep breeds, mainly used in clothing for its insulation properties. It makes up a small share of global fiber production, which is declining as synthetic fibers replace wool and meat farming becomes more profitable. Wool from slaughter sheep, often unsuitable for textiles, is treated as biodegradable waste. The aim of the study was to develop a fully biodegradable composite of natural origin from a polylactide (PLA) matrix reinforced with sheep wool and to select the optimal modifications (chemical) of sheep wool fibers to obtain modified properties, including mechanical properties. The behavior of the composites after exposure to aging conditions simulating naturally occurring stimuli causing biodegradation and thus changes in the material’s performance over its lifespan was also examined. Dynamic thermal analysis was used to describe and parameterize the obtained data and their variables, and the mechanical properties were investigated. The research culminated in a microscopic analysis along with changes in surface properties. The study demonstrated that wool-reinforced composites exhibited significantly improved resistance to UV degradation compared to pure PLA, with samples containing 15% unmodified wool showing a 54% increase in storage modulus at 0 °C after aging. Chemical modifications using nitric acid, iron compounds, and tar were successfully implemented to enhance fiber–matrix compatibility, resulting in increased glass transition temperatures and modified mechanical properties. Although wool fiber is not a good choice for modifications to increase mechanical strength, adding wool fiber does not improve mechanical properties but also does not worsen them much. Wool fibers are a good filler that accelerates degradation and are also a waste, which reduces the potential costs of producing such a biocomposite. The research established that these biocomposites maintain sufficient mechanical properties for packaging applications while offering better environmental resistance than pure polylactide, contributing to the development of circular economy solutions for agricultural waste valorization. So far, no studies have been conducted in the literature on the influence of sheep wool and its modified versions on the mechanical properties and the influence of modification on the degradation rate of PLA/sheep wool biocomposites.
