Szczegóły publikacji

Opis bibliograficzny

Determination of hydroxy derivatives of PAHs in sewage sludge by GC-MS/MS / Laura FRYDEL, Zuzanna PRUS, Karolina CWYNAR, Justyna Pamuła, Justyna PYSSA, Rosa Rego, Katarzyna STYSZKO // Desalination and Water Treatment ; ISSN 1944-3994. — 2025 — vol. 321 art. no. 101015, s. 1-10. — Bibliogr. s. 9-10, Abstr. — Publikacja dostępna online od: 2025-01-23

Autorzy (7)

Słowa kluczowe

OH-PAHsQuEChERSgas chromatographysewage sludgemass spectrometry

Dane bibliometryczne

ID BaDAP157884
Data dodania do BaDAP2025-03-04
Tekst źródłowyURL
DOI10.1016/j.dwt.2025.101015
Rok publikacji2025
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaDesalination and Water Treatment

Abstract

Polycyclic aromatic hydrocarbons (PAHs) are organic environmental contaminants, many of which pose serious health risks due to their persistence, toxicity and potential carcinogenicity. Their hydroxyl derivatives (OH-PAHs) are increasingly recognised as important contaminants in wastewater treatment systems because they are more water soluble, mobile and bioavailable than their parent PAHs. The aim of this study was to determine the content of common OH-PAHs in stabilised sewage sludge. The sediments were prepared by extraction using the QuEChERS method and analysed by GC-MS/MS technique. The results confirmed the highest levels of 1-naphthol and 2-naphthol in sludge samples collected in summer (78.1 ± 8.2 μg·kg‐1 and 126.9 ± 10.9 μg·kg‐1, respectively) compared to samples collected in winter (68.5 ± 9.3 μg·kg‐1 and 54.7 ± 9.7 μg·kg‐1, respectively). The concentrations of the remaining OH-PAHs were higher in winter than in summer. The highest content of OH-PAHs in summer was 2-naphthol (126.9 ± 10.9 μg·kg‐1) and the lowest was 2-fluorenol (1.17 ± 0.3 μg·kg‐1), and in winter 3-hydroxybenzo(a)pyrene (78.1 ± 7.4 μg·kg‐1) and 2-fluorenol (7.6 ± 0.7 μg·kg‐1). The validation parameters were within acceptable limits. The GC-MS/MS method demonstrated high accuracy and selectivity and can be successfully used for the detection and determination of OH-PAH concentrations in sewage sludge. Monitoring the content of OH-PAHs in wastewater systems provides information on the possible accumulation of these compounds in the environment and can therefore contribute to sustainable sludge management.

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#152869Data dodania: 16.5.2024
Application of the GC-MS/MS method for the determination of hydroxy derivatives of PAHs in sewage sludge / Zuzanna PRUS, Laura FRYDEL, Karolina CWYNAR, Jagoda WOREK, Katarzyna STYSZKO // W: CEwater [Dokument elektroniczny] : water and sewage in the circular economy model : international conference : April 22-24, 2024, [Cracow, Poland] : abstract book / Mineral and Energy Economy Research Institute Polish Academy of Sciences. — Wersja do Windows. — Dane tekstowe. — Cracow : Publishing House Mineral and Energy Economy Research Institute Polish Academy of Sciences, cop. 2024. — Iceland Lichtenstein Norway grants. — e-ISBN: 978-83-67606-37-0. — S. 62. — Wymagania systemowe: Adobe Reader. — Tryb dostępu: https://s.agh.edu.pl/2b43o [2024-04-24]
fragment książki
#154063Data dodania: 4.7.2024
Application of the GC-MS/MS method for the determination of hydroxyl derivatives of PAHS in particular matter / Karolina CWYNAR, Katarzyna STYSZKO, Zuzanna PRUS, Laura FRYDEL // W: EFE2024 [Dokument elektroniczny] : Energy Fuels Environment : international conference : 26-28 June 2024, Kraków, Poland : book of abstracts / ed. Bogdan Samojeden. — Wersja do Windows. — Dane tekstowe. — Kraków : [AGH University of Krakow], 2024. — e-ISBN: 978-83-969343-1-4. — S. 40. — Wymagania systemowe: Adobe Reader. — Tryb dostępu: https://efe2024.agh.edu.pl/wp-content/uploads/2024/06/Book-of... [2024-07-01]