Szczegóły publikacji
Opis bibliograficzny
Corrosion resistance of MgO and $Cr_{2}O_{3}$ - based refractory raw materials to PbO-rich Cu slag determined by hot-stage microscopy and pellet corrosion test / Maciej LUDWIG, Edyta ŚNIEŻEK, Ilona JASTRZĘBSKA, Ryszard PROROK, Yawei Li, Ning Liao, Mithun Nath, Jozef Vlček, Jacek SZCZERBA // W: Design, manufacturing and properties of refractory materials : special issue reprint / eds. Ilona Jastrzębska, Jacek Szczerba. — Basel : MDPI, cop. 2024. — ISBN: 978-3-7258-1089-5; e-ISBN: 978-3-7258-1090-1. — S. 266-288. — Bibliogr. s. 285-288, Abstr. — Reprinted from: Materials 2022, 15, 3, doi:10.3390/ma15030725. — M. Ludwig - dod. afiliacja: Forglass Sp. z. o. o., Kraków
Autorzy (9)
- AGHLudwig Maciej
- AGHŚnieżek Edyta
- AGHJastrzębska Ilona
- AGHProrok Ryszard
- Li Yawei
- Liao Ning
- Nath Mithun
- Vlček Jozef
- AGHSzczerba Jacek
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 153589 |
|---|---|
| Data dodania do BaDAP | 2024-06-13 |
| Tekst źródłowy | URL |
| Rok publikacji | 2024 |
| Typ publikacji | fragment książki |
| Otwarty dostęp |  |
| Creative Commons |
Abstract
Chemical resistance of commercial refractory raw materials against Cu slag is critical to consider them as candidates for the production of refractories used in Cu metallurgy. In this study, we show the comparative results for the corrosion resistance of four commercial refractory raw materials—magnesia chromite co-clinkers FMC 45 and FMC 57, PAK, and fused spinel SP AM 70—against aggressive, low-melting PbO-rich Cu slag (Z1) determined by hot-stage microscopy (up to 1450 °C) and pellet test (1100 and 1400 °C). Samples were characterized after the pellet test by XRD, SEM/EDS, and examination of their physicochemical properties to explore the corrosion reactions and then assess comparatively their chemical resistance. Since many works have focused on corrosion resistance of refractory products, the individual refractory raw materials have not been investigated so far. In this work, we show that magnesia chromite co-clinker FMC 45 exhibits the most beneficial properties considering its application in the production of refractories for the Cu industry. Forsterite (Mg2SiO4) and güggenite (Cu2MgO3) solid solutions constitute corrosion products in FMC 45, and its mixture with slag shows moderate dimensional stability at high temperatures. On the other hand, the fused spinel SP AM 70 is the least resistant to PbO-rich Cu slag (Z1); it starts to sinter at 970 °C, followed by a fast 8%-shrinkage caused by the formation of güggenite solid solution in significant amounts.
