Szczegóły publikacji
Opis bibliograficzny
Mo-doped $BaCe_{0·9}Y_{0·1}O_{3-\delta}$ proton-conducting electrolyte at intermediate temperature SOFCs. Pt. 1, Microstructure and electrochemical properties / Muhammad Bilal Hanif, Sajid Rauf, Michał Mosiałek, Kashif Khan, Vilma Kavaliukė, Algimantas Kežionis, Tomas Šalkus, Jacek Gurgul, Dmitry Medvedev, Małgorzata Zimowska, Dominika MADEJ, Martin Motola // International Journal of Hydrogen Energy ; ISSN 0360-3199. — 2023 — vol. 48 iss. 96, s. 37532–37549. — Bibliogr. s. 37545–37549, Abstr. — Publikacja dostępna online od: 2023-02-01
Autorzy (12)
- Hanif Muhammad Bilal
- Rauf Sajid
- Mosiałek Michał
- Khan Kashif
- Kavaliukė Vilma
- Kežionis Algimantas
- Šalkus Tomas
- Gurgul Jacek
- Medvedev Dmitry
- Zimowska Małgorzata
- AGHMadej Dominika
- Motola Martin
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 150227 |
|---|---|
| Data dodania do BaDAP | 2023-12-16 |
| DOI | 10.1016/j.ijhydene.2023.01.144 |
| Rok publikacji | 2023 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | International Journal of Hydrogen Energy |
Abstract
Researchers' interest in proton-conducting reversible solid oxide cells (RSOCs) is growing due to their distinct benefits. In the present work, single-phase BaCe0.9–xMoxY0.1O3–δ (x = 0, 0.025, 0.05, 0.1, 0.2) electrolyte is prepared via sol-gel method and sintered at 1400 °C for 10 h. Optimal density, structure, composition, electrochemical performance, and thermal stability are confirmed via SEM, XRD, EDS, XPS, FTIR, EIS, and TGA/DSC. The conductivity of the grain interior and boundaries between 127 and 727 °C is reported for the first time in SOFC studies. The BaCe0·875Mo0·025Y0·1O3–δ sample shows a grain interior conductivity of 1.3 × 10−3 S cm−1 at 707 °C with grain interior activation energy of 0.75 eV (127–727 °C), and a grain boundary activation energy of 0.85 eV (380–727 °C), 0.43 eV (167–357 °C) in air atmosphere, respectively. BaCe0.875Mo0.025Y0.1O3–δ showed extreme stability for 300 h, and thus can be considered suitable for an efficient protonic conductor at intermediate temperatures.
