Szczegóły publikacji

Opis bibliograficzny

Characterization of fly-ash cenospheres from coal-fired power plant unit / Maciej Żyrkowski, Rui Costa Neto, Luis F. Santos, Karol Witkowski // Fuel : the science and technology of fuel and energy ; ISSN 0016-2361. — 2016 — vol. 174, s. 49–53. — Bibliogr. s. 53, Abstr. — Publikacja dostępna online od: 2016-02-01. — M. Żyrkowski – afiliacje: Department of Mechanical Engineering, Instituto Superior Técnico, University of Lisbon ; CQE and Department of Chemical Engineering, Instituto Superior Técnico, University of Lisbon ; EDF Polska S. A.

Autorzy (4)

  • Żyrkowski Maciej
  • Neto Rui Costa
  • Santos Luís
  • Witkowski Karol

Słowa kluczowe

cenosphere formationcenospheresfly ashcenosphere yieldcoal combustion

Dane bibliometryczne

ID BaDAP144984
Data dodania do BaDAP2023-01-30
Tekst źródłowyURL
DOI10.1016/j.fuel.2016.01.061
Rok publikacji2016
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaFuel

Abstract

Cenospheres are one of the most desired byproducts of coal combustion process nowadays. They are small hollow spheres with roughly 10-1000 mu m in diameter and constitute about 1-2% of the fly ash obtained from the coal combustion processes. Because of their specific properties, namely their low density and high mechanical strength, cenospheres are an important subject of coal fired power plants. In this study, several fly ash samples from a coal-fired power plant located in Poland were analyzed in terms of fly ash composition, cenosphere content and its relation with glass formation principles and combustion conditions. The cenosphere samples, with different size, color and shape, were characterized, chemically and structurally, in order to establish the conditions that favor their formation. For this purpose, cenospheres have been collected and characterized by techniques such as SEM, EDS, XRD, XRF and Raman spectroscopy. Results indicate that cenospheres from coal combustion are constituted by aluminosilicate glasses with some crystalline phases like quartz, mullite and calcite. The high alumina content - roughly 25-27 wt.% - is responsible for the high mechanical strength, while density of most cenospheres is lower than 1 g/cm(3). Regarding the formation process, there are correlations between the amount of cenospheres and the sodium and calcium content, in the different fly ash samples.

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