Szczegóły publikacji
Opis bibliograficzny
Temperature-driven self-doping in magnetite / Hebatalla Elnaggar, [et al.], Wojciech TABIŚ, [et al.], Mateusz A. GALA, [et al.], Marcin SIKORA, [et al.] // Physical Review Letters ; ISSN 0031-9007. — 2021 — vol. 127 iss. 18 art. no. 186402, s. 186402-1–186402-5. — Bibliogr. s. 186402-4–186402-5. — Publikacja dostępna online od: 2021-10-29. — W. Tabiś – dod. afiliacja: Institute of Solid State Physics, TU Wien, Austria
Autorzy (12)
- Elnaggar Hebatalla
- Graas Silvester
- Lafuerza Bielsa Sara
- Detlefs Blanka
- AGHTabiś Wojciech
- AGHGala Mateusz
- Ismail Ahmed
- van der Eerden Ad
- AGHSikora Marcin
- Honig Jurgen M.
- Glatzel P.
- de Groot Frank M. F.
Dane bibliometryczne
ID BaDAP | 137782 |
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Data dodania do BaDAP | 2021-11-29 |
Tekst źródłowy | URL |
DOI | 10.1103/PhysRevLett.127.186402 |
Rok publikacji | 2021 |
Typ publikacji | artykuł w czasopiśmie |
Otwarty dostęp | |
Czasopismo/seria | Physical Review Letters |
Abstract
Magnetite is one of the most fascinating materials exhibiting the enigmatic first-order Verwey transition which is conventionally manipulated through chemical doping. Here, we show that heating magnetite results in a spontaneous charge reordering and, consequently, a hole self-doping effect at the octahedral sublattice. Core-level x-ray spectroscopy measurements combined with theory uncovers that there are three regimes of self-doping that map the temperature dependence of the electrical conductivity and magnetism up to the Curie temperature. Our results provide an elegant analogy between the effect of chemical doping and temperature-driven self-doping on trimerons in magnetite.