Szczegóły publikacji

Opis bibliograficzny

Effect of secondary carbon nanofillers on the electrical, thermal, and mechanical properties of conductive hybrid composites based on epoxy resin and graphite / Marcel ZAMBRZYCKI, Krystian SOKOŁOWSKI, Maciej GUBERNAT, Aneta FRĄCZEK-SZCZYPTA // Materials [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 1996-1944. — 2021 — vol. 14 iss. 15 art. no. 4169, s. 1–14. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 13–14, Abstr. — Publikacja dostępna online od: 2021-07-27

Autorzy (4)

Słowa kluczowe

carbon blackepoxyelectrical conductivitybipolar platesconductive polymer compositegraphitegraphene

Dane bibliometryczne

ID BaDAP135596
Data dodania do BaDAP2021-09-03
Tekst źródłowyURL
DOI10.3390/ma14154169
Rok publikacji2021
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaMaterials

Abstract

In this work, we present a comparative study of the impact of secondary carbon nanofillers on the electrical and thermal conductivity, thermal stability, and mechanical properties of hybrid conductive polymer composites (CPC) based on high loadings of synthetic graphite and epoxy resin. Two different carbon nanofillers were chosen for the investigation-low-cost multi-layered graphene nanoplatelets (GN) and carbon black (CB), which were aimed at improving the overall performance of composites. The samples were obtained by a simple, inexpensive, and effective compression molding technique, and were investigated by the means of, i.a., scanning electron microscopy, Raman spectroscopy, electrical conductivity measurements, laser flash analysis, and thermogravimetry. The tests performed revealed that, due to the exceptional electronic transport properties of GN, its relatively low specific surface area, good aspect ratio, and nanometric sizes of particles, a notable improvement in the overall characteristics of the composites (best results for 4 wt % of GN; sigma = 266.7 S cm(-1); lambda = 40.6 W mK(-1); fl. strength = 40.1 MPa). In turn, the addition of CB resulted in a limited improvement in mechanical properties, and a deterioration in electrical and thermal properties, mainly due to the too high specific surface area of this nanofiller. The results obtained were compared with US Department of Energy recommendations regarding properties of materials for bipolar plates in fuel cells. As shown, the materials developed significantly exceed the recommended values of the majority of the most important parameters, indicating high potential application of the composites obtained.

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