Szczegóły publikacji
Opis bibliograficzny
Influence of dry milling on phase transformation of sepiolite upon alkali activation: implications for textural, catalytic and sorptive properties / Anna Walczyk, Robert Karcz, Joanna Kryściak-Czerwenka, Bogna D. Napruszewska, Dorota Duraczyńska, Alicja Michalik, Zbigniew Olejniczak, Anna TOMCZYK, Agnieszka KLIMEK, Krzysztof BAHRANOWSKI, Ewa M. Serwicka // Materials [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 1996-1944. — 2020 — vol. 13 iss. 18, art. no. 3936, s. 1–24. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 20–24, Abstr. — Publikacja dostępna online od: 2020-09-05
Autorzy (11)
- Walczyk Anna
- Karcz Robert
- Kryściak-Czerwenka Joanna
- Napruszewska Bogna Daria
- Duraczyńska Dorota
- Michalik Alicja
- Olejniczak Zbigniew
- AGHTomczyk-Chmiel Anna
- AGHKlimek Agnieszka
- AGHBahranowski Krzysztof
- Serwicka-Bahranowska Ewa Maria
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 130089 |
|---|---|
| Data dodania do BaDAP | 2020-09-15 |
| Tekst źródłowy | URL |
| DOI | 10.3390/ma13183936 |
| Rok publikacji | 2020 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Creative Commons | |
| Czasopismo/seria | Materials |
Abstract
Activation of natural sepiolite by means of grinding in a planetary mill followed by wet NaOH activation was studied for the purpose of endowing the product with enhanced basicity for potential catalytic/sorptive applications. Synthesized solids were characterized with X-ray powder diffraction (XRD), N2 adsorption/desorption, scanning electron microscopy (SEM), energy dispersive (EDX), atomic absorption (AAS), Fourier-transform infrared (FTIR) and 29Si magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopies. Surface basicity was determined by titration with benzoic acid. Grinding changed the pathway of sepiolite phase transformation upon NaOH treatment. The as-received sepiolite evolved to Na-sepiolite (loughlinite) with a micropore system blocked by nanocrystalline Mg(OH)2, while ground samples yielded magnesium silicate hydrate phase (MSH), with well-developed microporous texture. In unmilled sepiolite desilication involved preferential leaching of Si from the center of the structural ribbons, while in ground samples additional loss of Si from ribbon-ribbon corner linkages was observed. In all cases treatment with NaOH led to enhancement of surface basicity. Synthesized materials were tested as catalysts in a base-catalyzed aldol self-condensation of acetone and oxidation of cyclohexanone to ε-caprolactone, as well as CO2 sorbents. Catalytic trends depended not only on samples’ basicity, but also on texture and phase composition of the catalysts. Grinding combined with alkali activation proved a simple and effective method for boosting CO2-sorption capacity of sepiolite to the level comparable to amine-functionalized, acid-activated sepiolite sorbents.
