Szczegóły publikacji

Opis bibliograficzny

Evaluation of pyrolysis and combustion products from foundry binders: potential hazards in metal casting / Angelika KMITA, Aleksandra BENKO, Agnieszka ROCZNIAK, Mariusz HOLTZER // Journal of Thermal Analysis and Calorimetry ; ISSN 1388-6150. — Tytuł poprz.: Journal of Thermal Analysis ; ISSN: 0368-4466. — 2020 — vol. 140 iss. 5, s. 2347–2356. — Bibliogr. s. 2355–2356, Abstr. — Publikacja dostępna online od: 2019-11-13


Autorzy (4)


Słowa kluczowe

combustionhazardous gaseous compoundsthermal decompositionpyrolysisenvironmentresole resin

Dane bibliometryczne

ID BaDAP128480
Data dodania do BaDAP2020-05-05
Tekst źródłowyURL
DOI10.1007/s10973-019-09031-9
Rok publikacji2020
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaJournal of Thermal Analysis and Calorimetry

Abstract

The aim of this paper is the comparison of the thermal destruction course of one of the commercially available binders applied in the ALPHASET technology in dependence of the temperature, heating rate and the character of the atmosphere (inert, oxidising or reducing). The thermogravimetric analysis/differential scanning calorimetry/Fourier-transform infrared spectroscopy (TG/DSC/FTIR) system allowed for real-time analysis of the composition and intensity of gases emitted during slow heating in the inert and oxidising atmospheres. In addition, the TG/DTG/DSC investigation of the binder was performed in the reducing atmosphere. The pyrolysis gas chromatography coupled with mass spectrometry system allowed for the analysis of gases evolved at very fast heating in the inert atmosphere (pyrolysis) as a function of temperature. It has been proven that the type and amount of the gases emitted is highly dependent on the temperature, heating rate and the atmosphere in which it is performed. The highest versatility of harmful volatiles is produced during heating in the inert atmosphere. This type of atmosphere is present in the closest proximity of the liquid metal. Thus, to reduce the risk of exposure of the foundry workers, the extraction of the casting should be done under the hood, and sufficient personal protective equipment should be used.

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