Szczegóły publikacji

Opis bibliograficzny

Recovery of zinc from steelmaking flue dust by hydrometallurgical route / E. RUDNIK // Archives of Metallurgy and Materials / Polish Academy of Sciences. Committee of Metallurgy. Institute of Metallurgy and Materials Science ; ISSN 1733-3490. — 2020 — vol. 65 iss. 2, s. 601–608. — Bibliogr. s. 608

Autor

Słowa kluczowe

recyclingleachingelectrowinningEAF dust

Dane bibliometryczne

ID BaDAP128310
Data dodania do BaDAP2020-04-27
Tekst źródłowyURL
DOI10.24425/amm.2020.132798
Rok publikacji2020
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaArchives of Metallurgy and Materials

Abstract

Industrial steelmaking (EAF) flue dust was characterized in terms of chemical and phase compositions, leaching behaviour in 20% sulphuric acid solution as well as leaching thermal effect. Waste product contained about 43% Zn, 27% Fe, 19% O, about 3% Pb and Mn and lesser amounts of other elements (Ca, Si, Mo, etc.). It consisted mainly of oxide-type compounds of iron and zinc. Dissolution of metals (Zn, Fe, Mn) from the dust was determined in a dependence of solid to liquid ratio (50-200 g/L), temperature (20-80oC) and leaching time (up to 120 min). The best result of 60% zinc recovery was obtained for 50 g dust/L and a temperature of 80oC. Leaching of the material was an exothermic process with a reaction heat of about -318 kJ/kg. Precipitation purification of the solution was realized using various ratios of H2O2 to NH3aq. A product of this stage was hydrated iron(III) oxide. Final solution was used for zinc electrowinning. Despite that pure zinc was obtained the highest cathodic current efficiency was only 40%. © 2020. The Author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial License (CC BY-NC 4.0, https://creativecommons.org/licenses/by-nc/4.0/deed.en which permits the use, redistribution of the material in any medium or format, transforming and building upon the material, provided that the article is properly cited, the use is noncommercial, and no modifications or adaptations are made.

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