Szczegóły publikacji
Opis bibliograficzny
Structure and electrical properties of $Fe–Mn–Co–O$ spinel / A. Kruk, T. BRYLEWSKI // Acta Physica Polonica. A ; ISSN 0587-4246. — 2019 — vol. 135 no. 3, s. 439–443. — Bibliogr. s. 443
Autorzy (2)
- Kruk Andrzej
- AGHBrylewski Tomasz
Dane bibliometryczne
ID BaDAP | 124897 |
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Data dodania do BaDAP | 2019-10-17 |
Tekst źródłowy | URL |
DOI | 10.12693/APhysPolA.135.439 |
Rok publikacji | 2019 |
Typ publikacji | artykuł w czasopiśmie |
Otwarty dostęp | |
Creative Commons | |
Czasopismo/seria | Acta Physica Polonica, A |
Abstract
Sub micro-sized Fe0.1Mn1.45Co1.45O4 powders were obtained using the sol-gel method with EDTA as a complexing agent. The sinters obtained from these powders were characterized by means of scanning electron microscopy, X-ray fluorescence, the Mossbauer spectroscopy, X-ray diffraction, and the 2-probe 4-point direct current method. The X-ray diffraction investigation of the sinter revealed that only the cubic phase had formed. Scanning electron microscopy showed that the sample was dense and exhibited a certain porosity. The addition of iron ions to the Mn1.5Co1.5O4 spinel reduced the electrical conductivity of the obtained sinter from ca. 60 to over 50 S/cm at 973 K. The Mossbauer studies showed the full incorporation of iron into the lattice structure of Mn-1.5Co(1).5O(4). In conclusion, the iron-doped spinel appears to be suitable for the surface modification of ferritic stainless steel substrates used in solid oxide fuel cells interconnects.