Szczegóły publikacji
Opis bibliograficzny
Combined $H_{2}O_{2}$/nitrile/bicarbonate system for catalytic Baeyer-Villiger oxidation of cyclohexanone to $\varepsilon$-caprolactone over $Mg-Al$ hydrotalcite catalysts / Robert Karcz, Joanna E. Olszówka, Bogna D. Napruszewska, Joanna Kryściak-Czerwenka, Ewa M. Serwicka, Agnieszka KLIMEK, Krzysztof BAHRANOWSKI // Catalysis Communications ; ISSN 1566-7367. — 2019 — vol. 132 art. no. 105821, s. 1–5. — Bibliogr. s. 4–5, Abstr. — Publikacja dostępna online od: 2019-09-11
Autorzy (7)
- Karcz Robert
- Olszówka Joanna E.
- Napruszewska Bogna Daria
- Kryściak-Czerwenka Joanna
- Serwicka-Bahranowska Ewa Maria
- AGHKlimek Agnieszka
- AGHBahranowski Krzysztof
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 124571 |
|---|---|
| Data dodania do BaDAP | 2019-10-08 |
| DOI | 10.1016/j.catcom.2019.105821 |
| Rok publikacji | 2019 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Catalysis Communications |
Abstract
Magnesium-aluminium hydrotalcite-like compounds (Ht) with molar ratios of Mg/Al = 2, 3, 4 and 6, were synthesized and used as catalysts in the Baeyer-Villiger oxidation of cyclohexanone to ε-caprolactone. Oxidation was carried out in mild conditions (70 °C, atmospheric pressure) either with conventional H2O2/acetonitrile oxidizing mixture, or with a newly designed H2O2/acetonitrile/bicarbonate system. The presented results show clearly superiority of bicarbonate-containing setup, which provides a significant increase of the ε-caprolactone yield. The neutralizing effect of bicarbonate, strongly limiting leaching of magnesium from Ht, is considered the main cause of the improved catalytic performance. © 2019 Elsevier B.V.
