Szczegóły publikacji

Opis bibliograficzny

Guar gum as an eco-friendly corrosion inhibitor for pure aluminium in 1-M HCl solution / Gaetano PALUMBO, Katarzyna BERENT, Edyta PRONIEWICZ, Jacek BANAŚ // Materials [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 1996-1944. — 2019 — vol. 12 iss. 16 art. no. 2620, s. 1–19. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 17–19, Abstr. — Publikacja dostępna online od: 2019-08-16


Autorzy (4)


Słowa kluczowe

pure aluminiumnatural inhibitorguar gumFTIRRamancorrosion inhibition

Dane bibliometryczne

ID BaDAP123754
Data dodania do BaDAP2019-10-03
Tekst źródłowyURL
DOI10.3390/ma12162620
Rok publikacji2019
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Creative Commons
Czasopismo/seriaMaterials

Abstract

Guar gum (GG) was investigated as a possible eco-friendly corrosion inhibitor for pure aluminium in a 1-M HCl solution at different temperatures and immersion times using gravimetric and electrochemical techniques. The results showed that GG was a good corrosion inhibitor for pure aluminium in the studied environment. The inhibition efficiency of GG increased with increasing inhibitor concentration and immersion time but decreased with increasing temperature. Polarisation measurements revealed that GG was a mixed type inhibitor with a higher influence on the cathodic reaction. The adsorption behaviour of the investigated inhibitor was found to obey the Temkin adsorption isotherm and the calculated values of the standard free adsorption energy indicate mixed-type adsorption, with the physical adsorption being more dominant. The associated activation energy (Ea) and the heat of adsorption (Qa) supported the physical adsorption nature of the inhibitor. Fourier-transform infrared spectroscopy (FTIR) and Raman/SERS were used to explain the adsorption interaction between the inhibitor with the surface of the metal. The results suggested that most inhibition action of GG is due to its adsorption of the metal surface via H-bond formation. © 2019 by the authors.

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