Szczegóły publikacji
Opis bibliograficzny
Preparation of azobenzene-intercalated kaolinite and monitoring of the photoinduced activity / Anna KOTEJA, Jakub MATUSIK // Clay Minerals : Journal of the European Clay Groups ; ISSN 0009-8558. — 2019 — vol. 54 iss. 1, s. 57–66. — Bibliogr. s. 65–66, Abstr. — Publikacja dostępna online od: 2019-02-07
Autorzy (2)
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 121869 |
|---|---|
| Data dodania do BaDAP | 2019-07-19 |
| Tekst źródłowy | URL |
| DOI | 10.1180/clm.2019.6 |
| Rok publikacji | 2019 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Clay Minerals |
Abstract
Systems consisting of layered structures and photoactive molecules have been studied extensively. The structures of resulting complexes may be controlled by UV-Vis radiation, which subsequently affects their materials properties. This study describes a synthesis route for obtaining a photoresponsive kaolinite intercalation compound. The material was prepared by co-intercalating azobenzene and benzylalkylammonium chlorides into a methoxy form of kaolinite. The resultant materials possessed large basal spacing values in the range of 45-55 angstrom. The UV-Vis and Fourier-transform infrared spectroscopy analyses confirmed the reversible photoisomerization of azobenzene upon exposure to UV and Vis radiation. This phenomenon was significantly influenced by the type and amount of co-intercalated molecules. Upon multiple trans-cis conversions, the azobenzene partially evaporated. For the first time, a kaolinite-based material was prepared that exhibited photochromic behaviour upon UV and Vis irradiation.
