Szczegóły publikacji
Opis bibliograficzny
Determination of the activities of cobalt and nickel orthosilicates in $\{xCo_{2}SiO_{4}+(1-x)Ni_{2}SiO_{4}\}$ using a solid-state galvanic cell method / G. RÓG, A. KOZŁOWSKA-RÓG // Journal of Chemical Thermodynamics ; ISSN 0021-9614. — 2002 — vol. 34 no. 8, s. 1151–1156. — Bibliogr. s. 1155–1156
Autorzy (2)
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 11993 |
|---|---|
| Data dodania do BaDAP | 2003-02-27 |
| Tekst źródłowy | URL |
| DOI | 10.1006/jcht.2002.0971 |
| Rok publikacji | 2002 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp | |
| Czasopismo/seria | Journal of Chemical Thermodynamics |
Abstract
The {xCo(2)SiO(4) + (1 - x)Ni2SiO4} solid solutions were studied at the temperatures of (1073, 1173 and 1273) K by solid-state galvanic cells involving beta"-alumina electrolytes conducting cobalt and nickel divalent ions, respectively. The activities of both components of the solid solution were determined directly from the e.m.f. measurements. The solutions exhibited positive deviations from Raoult's law and could be characterized as regular solutions. (C) 2002 Elsevier Science Ltd. All rights reserved.