Szczegóły publikacji
Opis bibliograficzny
Phase transition and thermal decomposition of $[Cd(H_{2}O)_{6}](BF_{4})_{2}$ / E. Mikuli, A. Migdał-Mikuli, R. GAJERSKI // Journal of Thermal Analysis and Calorimetry ; ISSN 1388-6150. — Tytuł poprz.: Journal of Thermal Analysis ; ISSN: 0368-4466. — 2002 — vol. 68 iss. 3, s. 861–864. — Bibliogr. s. 864, Abstr. — CCTA 8 Meeting : Zakopane, Poland, September, 2000
Autorzy (3)
- Mikuli Edward
- Migdał-Mikuli Anna
- AGHGajerski Ryszard
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 11983 |
|---|---|
| Data dodania do BaDAP | 2003-02-27 |
| Tekst źródłowy | URL |
| DOI | 10.1023/A:1016126102891 |
| Rok publikacji | 2002 |
| Typ publikacji | referat w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Journal of Thermal Analysis and Calorimetry |
Abstract
Phase transition and thermal decomposition of [Cd(H2O)(6)] (BF4)(2) were studied by differential scanning calorimetry (DSC), differential thermal analysis (DTA) and thermogravimetry (TG) methods. The solid-solid phase transition at T-Cl = 324 K and the melting point at T-melt. = 391 K were registered. The thermal dehydration process starts just above T-Cl and continues up to T-melt., where [Cd(H2O)(4)] (BF4) (2) in the liquid phase is formed. Then, dehydration and decomposition take place simultaneously until CdF2 is obtained. Final products of the thermal decomposition were identified using quadrupole mass spectrometry (QMS) and X-ray diffraction methods.
