Szczegóły publikacji

Opis bibliograficzny

Experimental and theoretical studies of structural and electrical properties of highly porous $Sr_{1-x}Y_{x}TiO_{3}$ / Ewa DROŻDŻ, Agnieszka ŁĄCZ, Andrzej KOLEŻYŃSKI, Andrzej MIKUŁA, Krzysztof MARS // Solid State Ionics ; ISSN  0167-2738 . — 2017 — vol. 302, s. 173–179. — Bibliogr. s. 179, Abstr. — Publikacja dostępna online od: 2016-11-21. — ISSFIT-12 : 12th International Symposium on Systems with Fast Ionic Transport : Kaunas, Lithuania, July 3–7, 2016

Autorzy (5)

Słowa kluczowe

electrical propertieshighly porous SrTiO3mixed electron-ionic conductivityab initio calculationsSOFC anode

Dane bibliometryczne

ID BaDAP106987
Data dodania do BaDAP2017-09-01
Tekst źródłowyURL
DOI10.1016/j.ssi.2016.11.014
Rok publikacji2017
Typ publikacjireferat w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaSolid State Ionics

Abstract

A series of highly porous Sr1-xYxTiO3 samples (with x = 0, 2, 4, 6 and 8 mol%) were prepared by sol-gel method and sintered at 1200 C. Single phase materials were obtained for up to 6 mol% of yttrium admixture as confirmed by XRD measurements. For samples with 8 mol% of dopant, traces of Y2Ti2O7 phase were found indicating yttrium solubility limit in this structures at below 8 mol%. For all samples electrochemical impedance spectroscopy measurements were carried out in air and hydrogen (reduced) atmosphere. In order to determine conductivity type, Seebeck coefficient was measured under reduced conditions. Additionally, for a series of selected model structures, corresponding to experimental compositions, FP-LAPW DFT calculations of electronic structure and bonding properties (using QTAiM approach) were performed.

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