Szczegóły publikacji

Opis bibliograficzny

Raman spectroscopic and microthermometric studies of authigenic quartz (the Pepper Mts., Central Poland) as an indicator of fluids circulation / Beata NAGLIK, Tomasz TOBOŁA, Lucyna NATKANIEC-NOWAK, Jarmila Luptáková, Stanislava Milovská // Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy ; ISSN 1386-1425. — 2017 — vol. 173, s. 960–964. — Bibliogr. s. 964, Abstr. — Publikacja dostępna online od: 2016-10-29

Autorzy (5)

Słowa kluczowe

Raman spectroscopyfluid inclusionPepper Mountainsauthigenic quartzmicrothermometry

Dane bibliometryczne

ID BaDAP106651
Data dodania do BaDAP2017-08-29
Tekst źródłowyURL
DOI10.1016/j.saa.2016.10.047
Rok publikacji2017
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaSpectrochimica Acta, Part A, Molecular and Biomolecular Spectroscopy

Abstract

Differently colored authigenic quartz crystals were found as the druses compound within mudstone heteroliths from the Pepper Mts. Shale Formation (Cambrian unit of the Holy Cross Mts., Central Poland). The genesis of this mineral was established on the basis of fluid inclusion study. Raman microspectroscopy was the key instrumental technique to identify the nature of the compounds trapped in the fluid inclusions. Methane (2917 cm(-1)) or water vapor (broad band-2500-3000 cm(-1)) occur within two-phased primary inclusion assemblages, while nitrogen (2329 cm(-1)) associated with methane and trace amount of carbon dioxide (1285, 1388 cm(-1)) occur within secondary fluid inclusion assemblage. Temperatures of homogenization of primary fluid inclusions was obtained on the basis of heating experiments and ranged from 171 degrees to 266 degrees C. These values are much higher than expected for the diagenetic system without metamorphic changes what may imply hydrothermal origin of quartz crystals. The source of fluids is uncertain as in the Holy Cross Mts. there was no volcanic activity to the end of Late Devonian. However, fluids originated in metamorphic basin could use deep faults as the migration paths. (C) 2016 Elsevier B.V. All-rights reserved.

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