Szczegóły publikacji
Opis bibliograficzny
On fabrication procedures of Li-ion conducting garnets / Emil Hanc, Wojciech ZAJĄC, Li Lu, Binggong Yan, Masashi Kotobuki, Magdalena ZIĄBKA, Janina MOLENDA // Journal of Solid State Chemistry ; ISSN 0022-4596. — 2017 — vol. 248, s. 51–60. — Bibliogr. s. 60, Abstr. — Publikacja dostępna online od: 2017-01-17
Autorzy (7)
- Hanc Emil
- AGHZając Wojciech
- Lu Li
- Yan Binggong
- Kotobuki Masashi
- AGHZiąbka Magdalena
- AGHMolenda Janina
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 104764 |
|---|---|
| Data dodania do BaDAP | 2017-04-03 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.jssc.2017.01.017 |
| Rok publikacji | 2017 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp | |
| Czasopismo/seria | Journal of Solid State Chemistry |
Abstract
Ceramic oxides exhibiting high lithium-ion mobility at room temperature receive broad attention as candidate electrolytes for lithium batteries. Lithium-stuffed garnets from the Li7La3Zr2O12 group seem to be especially promising because of their high ionic conductivity at room temperature and their electrochemical stability. In this work, we discuss factors that affect formation of the garnet in its bulk form or in the form of thick and thin films. We demonstrate that zinc oxide can be applied as a sintering aid that facilitate the formation of the highly conducting cubic Li7La3Zr2O12 garnet phase in a single-step sintering procedure. Based on our experience with the single-step sintering experiments, we successfully fabricated a thick-film membrane consisting of a garnet solid electrolyte using the tape casting technique. In order to reduce the thickness of the electrolyte even further we investigated the fabrication of a thin-film Li7La3Zr2O12 electrolyte by means of the pulsed laser deposition technique.