Szczegóły publikacji
Opis bibliograficzny
Ultrasensitive catalytic-adsorptive stripping voltammetric determination of molybdenum using a Mo(VI)-chloranilic acid-chlorate system / Jerzy ZARĘBSKI, Andrzej BOBROWSKI, Agnieszka KRÓLICKA, Rafał Bobrowski, Katarzyna Kwaśniewska // Electrochimica Acta : Journal of the International Society of Electrochemistry ; ISSN 0013-4686. — 2016 — vol. 208, s. 267–272. — Bibliogr. s. 271–272, Abstr. — Publikacja dostępna online od: 2016-05-07
Autorzy (5)
- AGHZarębski Jerzy
- AGHBobrowski Andrzej
- AGHKrólicka Agnieszka
- Bobrowski Rafał
- Kwaśniewska Katarzyna
Słowa kluczowe
Dane bibliometryczne
| ID BaDAP | 104526 |
|---|---|
| Data dodania do BaDAP | 2017-03-31 |
| Tekst źródłowy | URL |
| DOI | 10.1016/j.electacta.2016.04.113 |
| Rok publikacji | 2016 |
| Typ publikacji | artykuł w czasopiśmie |
| Otwarty dostęp |  |
| Czasopismo/seria | Electrochimica Acta |
Abstract
A catalytic adsorptive stripping voltammetric procedure of the determination of ultratrace amounts of molybdenum using a novel catalytic system, Mo(VI)-chloranilic acid-chlorate was elaborated. In a supporting electrolyte containing 0.01 M HCl (pH 2), 2.5 x 10(-4) M chloranilic acid and 0.4 M KClO3, the catalytic adsorptive stripping response observed at -0.23 V was proportional to the Mo(VI) concentration within the range of 0.16 mu gl(-1) to 60 mu gl(-1) for 60 s of accumulation. The limit of detection was found to be 1.6 x 10(-10) M. The reproducibility of the blank signal was equal to 4.8%. The method was validated by quantifying Mo(VI) in certified reference surface water, and it was applied for the determination of Mo (VI) in extracts of fly ashes. The possible scheme of the catalytic reaction was suggested.
