Szczegóły publikacji
Opis bibliograficzny
Sn-bearing minerals and associated sphalerite from lead-zinc deposits, Kosovo: an electron microprobe and LA-ICP-MS study / Joanna KOŁODZIEJCZYK, Jaroslav PRŠEK, Panagiotis Voudouris, Vasilios Melfos, Burim Asllani // Minerals [Dokument elektroniczny]. — Czasopismo elektroniczne ; ISSN 2075-163X. — 2016 — vol. 6 iss. 2 art. no. 42, s. 1–17. — Wymagania systemowe: Adobe Reader. — Bibliogr. s. 15–17, Abstr. — Publikacja dostępna online od: 2016-05-06
Autorzy (5)
- AGHKołodziejczyk Joanna
- AGHPršek Jaroslav
- Voudouris Panagiotis Ch.
- Melfos Vasilios
- Asllani Burim
Słowa kluczowe
Dane bibliometryczne
ID BaDAP | 100777 |
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Data dodania do BaDAP | 2016-09-30 |
Tekst źródłowy | URL |
DOI | 10.3390/min6020042 |
Rok publikacji | 2016 |
Typ publikacji | artykuł w czasopiśmie |
Otwarty dostęp | |
Creative Commons | |
Czasopismo/seria | Minerals |
Abstract
Stannite group minerals (ferrokesterite and stannite) occur in small amounts in association with sulfides in hydrothermal Pb-Zn deposits in Kosovo. The chemical composition of sphalerite co-existing with Sn-bearing minerals has been investigated using laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS). Flat Sn-spectra suggest that Sn is bound in the sphalerite lattice or as nanoincluions. Sphalerite from Stan Terg, overgrown by ferrokesterite, contains the lowest Sn content (few ppm) and have been precipitated before Sn-enrichment in the fluids. The highest value of Sn (520 ppm) of Stan Terg sphalerite was obtained directly close to the ferrokesterite rim, and indicates a rapid increase of Sn in the hydrothermal fluids. Significantly higher values of Sn in sphalerite were obtained from other deposits: 1600 ppm (Artana), up to 663 ppm (Kizhnica), up to 2800 ppm (Drazhnje). Stannite-sphalerite geothermometry revealed the following ore-forming temperatures for the Kosovo mineralization: 240-390 degrees C for Stan Terg, 240-370 degrees C for Artana, >340 degrees C for Kizhnica, and 245-295 degrees C for Drazhnje. Sphalerite and stannite group minerals precipitated simultaneously during cooling from reduced hydrothermal fluids and under low-sulfidation fluid states. Fluctuations in physico-chemical fluid conditions are evidenced by the presence of stannite group minerals along growth zones in sphalerite and may be related to short interval of magmatic pulses during ore deposition.