Szczegóły publikacji

Opis bibliograficzny

2–3 $\mu$m mid-infrared luminescence of $Ho3^{+}/Yb^{3+}$ co-doped chloride-modified fluorotellurite glass / Dingchen Tang, Ying Tian, Dominik DOROSZ, Xu Wang, Xueying Yang, Yongyan Liu, Xianghua Zhang, Junjie Zhang, Shiqing Xu // Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy ; ISSN 1386-1425. — 2023 — vol. 285 art. no. 121833, s. 1–10. — Bibliogr. s. 9–10, Abstr. — Publikacja dostępna online od: 2022-09-03


Autorzy (9)


Słowa kluczowe

chloride-modified fluorotellurite glassmaximum phonon energymid-infrared fluorescencequantum efficiency

Dane bibliometryczne

ID BaDAP143197
Data dodania do BaDAP2022-11-16
Tekst źródłowyURL
DOI10.1016/j.saa.2022.121833
Rok publikacji2023
Typ publikacjiartykuł w czasopiśmie
Otwarty dostęptak
Czasopismo/seriaSpectrochimica Acta, Part A, Molecular and Biomolecular Spectroscopy

Abstract

In this paper, Ho3+/Yb3+ co-doped chloride-modified fluorotellurite glasses with 2–3 μm mid-infrared luminescence are prepared. By measuring and investigating the transmission spectra and emission spectra, the prepared glasses show a high transmittance (91 %) and low maximum phonon energy (813 cm−1). Based on the measured absorption spectra, the Judd-Ofelt parameters and radiation characteristics were calculated in depth. In addition, with the assistance of phonons, the energy transfer between Ho3+/Yb3+ ions further increases the mid-infrared fluorescence intensity. The calculated emission cross-section at 2.0 μm and 2.85 μm reach 16.47 × 10-21 cm2 and 7.8 × 10-21 cm2, respectively. It is worth mentioning that the quantum efficiencies of Ho3+: 5I7→5I8 and 5I6→5I7 reach 51.47 % and 84.14 % respectively. The results having also in mind good thermal stability (ΔT = 102℃) and refractive index (n = 1.645) indicate that this glass has a promising application for the study of fiber lasers in the mid-infrared band.

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